192 research outputs found
Nitrogen fractionation in high-mass star-forming cores across the Galaxy
No full textThe fractionation of nitrogen (N) in star-forming regions is a poorly understood process. To put more stringent observational constraints on the N-fractionation, we have observed with the IRAM-30-m telescope a large sample of 66 cores in massive star-forming regions. We targeted the (1-0) rotational transition of HN13C, HC15N, H13CN and HC15N, and derived the 14N/15N ratio for both HCN and HNC. We have completed this sample with that already observed by Colzi et al., and thus analysed a total sample of 87 sources. The 14N/15N ratios are distributed around the Proto-Solar Nebula value with a lower limit near the TA value (∼272). We have also derived the 14N/15N ratio as a function of the Galactocentric distance and deduced a linear trend based on unprecedented statistics. The Galactocentric dependences that we have found are consistent, in the slope, with past works but we have found a new local 14N/15N value of ∼400, i.e. closer to the Prosolar Nebula value. A second analysis was done, and a parabolic Galactocentric trend was found. Comparison with Galactic chemical evolution models shows that the slope until 8 kpc is consistent with the linear analysis, while the flattening trend above 8 kpc is well reproduced by the parabolic analysis
A new satellite experiment in the Q/V band for the verification of fade countermeasures based on the spatial non-uniformity of attenuation
No full textDC3N observations towards high-mass star-forming regions
No full textWe present the study of deuteration of cyanoacetylene (HC3N) towards a sample of 28 high-mass star-forming cores divided into different evolutionary stages, from starless to evolved protostellar cores. We report for the first time the detection of DC3N towards 15 high-mass cores. The abundance ratios of DC3N with respect HC3N range in the interval 0.003-0.022, lower than those found in low-mas protostars and dark clouds. No significant trend with the evolutionary stage, or with the kinetic temperature of the region, has been found. We compare the level of deuteration of HC3N with those of other molecules towards the same sample, finding weak correlation with species formed only or predominantly in gas phase (N2H+ and HNC, respectively), and no correlation with species formed only or predominantly on dust grains (CH3OH and NH3, respectively). We also present a single-dish map of DC3N towards the protocluster IRAS 05358+3543, which shows that DC3N traces an extended envelope (similar to 0.37 pc) and peaks towards two cold condensations separated from the positions of the protostars and the dust continuum. The observations presented in this work suggest that deuteration of HC3N is produced in the gas of the cold outer parts of massive star-forming clumps, giving us an estimate of the deuteration factor prior to the formation of denser gas
Reaction of Alkynes with Iodine Monochloride Revisited
No full text6-Exo-dig and/or 7-endo-dig iodocyclization reactions
of functionalized acetylenic derivatives with ICl are
disfavored in comparison with the corresponding electrophilic
addition reactions providing regioselectively (E)-1-
chloro-2-iodoethene derivatives. On the contrary, 6-endo-dig
and 5-exo-dig iodocyclizations of methyl ynoates with ICl
seem to be favored in comparison with the corresponding
electrophilic addition reactions
First interferometric study of enhanced N-fractionation in N2H+: The high-mass star-forming region IRAS 05358+3543
No full textNitrogen (N)-fractionation is used as a tool to search for a link between the chemical history of the Solar system and star-forming regions. A large variation of 14N/15N is observed towards different astrophysical sources, and current chemical models cannot reproduce it. With the advent of high angular resolution radiotelescopes it is now possible to search for N-fractionation at core scales. We present IRAM NOEMA observations of the J = 1-0 transition of N2H+15NNH+, and N15NH+ towards the high-mass protocluster IRAS 05358+3543. We find 14N/15N ratios that span from ∼100 up to ∼220 and these values are lower or equal to those observed with single-dish observations towards the same source. Since N-fractionation changes across the studied region, this means that it is regulated by local environmental effects. We find also the possibility, for one of the four cores defined in the protocluster, to have a more abundant 15NNH+ with respect to N15NH+. This is another indication that current chemical models may be missing chemical reactions or may not take into account other mechanisms, like photodissociation or grain surface chemistry, that could be important
Adolescente con Tachicardia recidivante a complessi larghi: condizioni diagnostico-terapeutiche iniziali.
No full textMetabolic Responses in Leaves of 15 Italian Olive Cultivars in Correspondence to Variable Climatic Elements
No full textThis study aims to evaluate the metabolic changes that occurred in olive leaves as responses over time to variations in climatic elements. Rainfall, temperature, and solar radiation data were collected over 4 months (August–November) to assess the impact of different climatic trends on the metabolism of the leaves of 15 Italian olive cultivars, cultivated at the experimental farm of the University of Florence. The net photosynthetic rate (AN) and stomatal conductance (gs), measured as main indicators of primary metabolism, were mainly influenced by the “cultivar” effect compared to the “climate” effect. The lowest AN value was showed by “Bianchera”, while “Ascolana” recorded the highest (8.6 and 13.6 μmol CO2 m−2s−1, respectively). On the other hand, the secondary metabolism indicators, volatile organic compound (VOC) and oleuropein (OL) content, were much more influenced by climate trends, especially rainfall. A phase of high rainfall caused a significant increase in the VOCs emission from leaves, even with different behaviors among the genotypes. The highest differences were observed between “Maiatica di Ferrandina”, with the highest average values (~85,000 npcs), and “Frantoio”, which showed the lowest (~22,700 npcs). The OL content underwent considerable fluctuations in relation to the rainfall but also appeared to be controlled by the genotype. “Coratina” always showed the highest OL concentration (reaching the maximum ~98 mg g−1), indicating the great potential of this cultivar for the industrial recovery of OL
Sweet Chestnut Wood Distillate’s Role in Reducing Helicoverpa armigera Damage and Enhancing Chickpea Performance: Evidence from Field Trial
No full textThe moth Helicoverpa armigera (Lepidoptera: Noctuidae), better known as the pod borer, poses significant threats to chickpea (Cicer arietinum L.) production. Therefore, effective and sustainable crop management strategies are required to mitigate the impact of this cosmopolitan pest. The present study aimed at investigating the potential of wood distillate (WD), a liquid byproduct of the pyrolysis of waste lignocellulosic biomass, to both reduce H. armigera pest incidence and to enhance crop yields in field-grown chickpea. The application of WD as a foliar spray effectively reduced the number of damaged pods by 35% during the plant´s reproductive stage compared with water-sprayed plants (~16 vs. 24 bored pods plant−1, respectively) and increased the number of healthy pods (~16 vs. 10 pods plant−1, respectively). Moreover, the lower pest incidence was accompanied by an improvement of both the seed yield and the quality at the plant´s full maturity stage. Specifically, WD-treated plants increased both the number and weight of seeds by ~80% compared to water-sprayed plants (~23 vs. 13 and 5.5 vs. 3 plant−1, respectively) which further showed a remarkable improvement in their nutritional value, with the concentration of total polyphenols, flavonoids, starch, calcium, and magnesium increasing by 17%, 56%, 43%, 23%, and 15%, respectively. These results underscore the potential of WD to both improve chickpea performance and to reduce H. armigera damage to sustainably improve the productivity of this critical legume crop, aligning with the principles of the circular economy and offering an environmentally friendly alternative to synthetic pesticides and fertilizers in agriculture
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