3,144 research outputs found

    Interview with Darrell Sanders, Cully Community Garden, 2010 (audio)

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    Interview of Darrell Sanders by Jeremy Cohen in Portland, Oregon on February 20th, 2010. The interview index is available for download

    Sanders’ Pictorial Primer

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    Sanders’ Pictorial Primer, or, An Introduction to Sanders’ First Reader, enl. and rev. by Charles W. Sanders. A primary reader with illustrations and words for children.At head of title: Sanders’ series. The name of J.C. Sanders appears on t.-p. of 1846 edition as joint author. Cover title: The green primer

    Roberto Lopez Valencia vs. Eric Holder Jr.

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    BC Law third-year students Kelly Schwartz and Jeremy Sanders address the Ninth Circuit Court of Appeals in California, part of the Ninth Circuit Appellate Project clinic at BC Law

    Persuasion through emotions in Athenian deliberative oratory

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    © 2016, Franz Steiner Verlag. The attached document (embargoed until 31/10/2017) is an author produced version of a chapter uploaded in accordance with the publisher’s self- archiving policy. Sanders, E. (2016). Persuasion through emotions in Athenian deliberative oratory. In E. Sanders, & M. Johncock (Eds.), Emotion and persuasion in classical antiquity (pp. 57-73). Stuttgart: Franz Steiner Verlag

    Introduction

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    © 2016, Franz Steiner Verlag. The attached document (embargoed until 31/10/2017) is an author produced version of a chapter uploaded in accordance with the publisher’s self- archiving policy. Sanders, E. (2016). Introduction. In E. Sanders, & M. Johncock (Eds.), Emotion and persuasion in classical antiquity (pp. 13-24). Stuttgart: Franz Steiner Verlag

    Diary of C. J. Sanders

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    Diary - This document is the personal diary of Constance Jukes Sanders, daughter of Gilbert E. Sanders, Superintendent of the Northwest Mounted Police 1905-1908. The diary begins on August 27, 1910, and ends April 6, 1911. Diary entries include daily activities of C. J. Sanders during her nineteenth and twentieth years, while living in Athabasca Landing with her parents. C. J. spent her days doing housework at the family's home, and often taught Sunday School at the local church. A favourite pastime was having friends over to play bridge in the evening, or riding ponies during the daytime. Church was a big part of the family's week. The women also spent a lot of time cooking, cleaning and sewing. C. J. took a boat over to Europe with her mother and father just before Christmas in 1910. She was very seasick during the trip. While in Europe they visited family and friends in England, Ireland and France (45 pages

    Ruthenium(ii) and rhodium(iii) porphyrin phosphine complexes: influence of substitution pattern on structure and electronic properties

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    A series of ruthenium(II) and rhodium(III) porphyrin complexes with diphenyl phenylacetylene phosphine (dpap) was synthesised and fully characterised by UV-vis, 1H NMR and 31P{1H} NMR spectroscopy, and in most cases also by single-crystal X-ray diffraction. The substitution pattern of the porphyrin was varied with increasing meso-phenyl substitution, from octa-ethyl porphyrin (OEP), through diphenyl di-ethyl porphyrin (DPP), to tetraphenyl porphyrin (TPP) and 3,5-di-tbutyl tetraphenyl porphyrin (tbTPP). The dpap readily displaces the CO ligand from the parent Ru(CO)(porphyrin) and the iodide from the Rh(I)(porphyrin) to give bis-phosphine complexes M(dpap)2(porphyrin). The UV-vis spectra reveal that some of the complexes are partially dissociated at concentrations of 10?6 M, and the association constants were estimated to be in the range of 106 to 107 M?1 for the first, and 104 to 106 M?1 for the second binding event. The 1H NMR chemical shifts of the complexes vary greatly despite the fact that they display very similar geometries in the solid state, and no correlation could be discerned between the crystal structures and the spectroscopic parameters in solutio

    Matrix assisted laser desorption/ionisation (MALDI)-TOF mass spectrometry of supramolecular metalloporphyrin assemblies: a survey

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    Analysis of a representative series of metalloporphyrins and of their supramolecular assemblies using laser desorption/ionisation time of flight mass spectrometry (LDI-TOF MS) revealed that non-covalent metal-ligand interactions in the complexes remain effective in the gas phase. Detectable assemblies range from simple ruthenium(II) porphyrin complexes with N- or P-donor ligands, or tin(IV) and zirconium(IV) porphyrin complexes with O-donor ligands, up to trimeric arrays. Crucial to successful recording of intact complexes is avoiding protic matrices which interfere with Lewis acidic analytes and which may induce ligand exchange reactions to form complexes with the matrix itself. Also described is the in situ generation of a series of ruthenium(II) porphyrin dimers via laser induced vaporisation of the corresponding monomers and the suppression of dimerisation by nitrogen and phosphorus ligands. Careful adjustment of instrument parameters such as incident laser energy requires special attention. relative affinities in complexation reactions are found to be consistent with liquid phase chemistry, therefore LDI-MS can provide a fast and simple, yet effective screening method for reactivity exploration. however, it also induces side-reactions such as iodine abstraction/transfer reactions. Furthermore, structurally different porphyrins show variations up to 90% in relative ion formation. Extreme caution is therefore required in the interpretation, and particularly in the quantitation, of such mass spectra
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