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    Continuous direct ink jet printing.

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    PhDThis thesis describes the preparation and continuous printing of zirconia ink under different conditions, as well as the development of silver inks, for the same purpose. The dispersion of sub-micrometer zirconia powder in industrial methylated spirit using other additives such as dispersant and binder was investigated with different mixing methods and at varying powder and binder contents. The use of high shear mixing by triple roll milling followed by ultrasonic disruption as well as adequate sedimentation and filtration produced a homogeneous and stable ink of 2.5 vol. % ZrO2. The ink could be printed directly and continuously on a commercial jet printer without interruption of any kind and the phenomena occurring during printing were investigated. The optimum modulation frequency for printing was determined with the generation of pear-shaped and symmetrical droplets. Printing was made on substrates of surface free energies lower and higher than the surface tension of the Zr02 ink. Powder migration was observed within a relic of the printed dot on the second type of substrate. Layers were also overprinted on the second type of substrate by varying the following: print resolution, printing interval, print area, drying conditions and ink powder loading. These series of prints were accompanied by the appearance of ridges, spattering and non-vertical walls and the effects were investigated. The wettability and shrinkage of droplets of the ceramic ink was also studied in-situ by monitoring the evolution of contact angle, width of ink-substrate interface and droplet height with a video camera. The shape of the droplet experienced different dynamics on different types of substrate. Lastly, the sedimentation behaviour of ethanol-based silver inks dispersed with different types of dispersant was investigated with respect to the sediment volume and half-value time. Deflocculated ink was obtained at a low dispersant level and powder loading

    Visualization of toner ink adsorption at bubble surfaces

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    Flotation deinking involves interactions between inks particles and bubbles surfaces. These interactions are very difficult to observe directly or to quantify in bench-scale experiments or mill operations, making it difficult to evaluate effects of process conditions such as bubble size and solution chemistry on deinking efficiency. This paper presents images and measurements of toner ink interactions with bubble surfaces in laboratory-scale flotation processes. Stable adsorption of toner ink was observed at surfaces of stationary and suspended bubbles for several system chemistries. Interactions of toner particles and bubbles were quantified by high magnification and high temporal resolution digital videos obtained in bubble flow facilities creating both stationary and flowing bubbles. Large (>200 micron), flat toner particles adsorbed to bubble surfaces by single contact points. Smaller toner particles formed very stable complexes in fatty acid chemistries. Desorption of toner ink from bubble surfaces was not observed, even for vigorous flows. Bubbles were observed to be fully covered with toner after 4 minutes of residence time in the suspending bubble flow facility. Initial estimates indicate that bubbles with diameters of approximately 1 mm carry more than 1 mg of ink per bubble

    The use of embellishment techniques with ink jet printed repeated designs

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    This paper will discuss the use of devore printing as an additional design feature to ink jet printed fabrics. Ink jet printed fabrics are an ideal basis for bespoke fabrics to be generated in small-scale productions. To begin with this paper will discuss the production of ink jet printed fabrics in repeat using textile CAD software. The original design will include all embellishments as part of the original repeat; as an overlay. Before the application of a devore effect, the ink jet printed fabric will need to be finished conventionally, then the shrinkage which occurs can be taken into consideration and the overlay modified in repeat. To conclude the paper will discuss the extension of this process into other possible methods of embellishment such as overprinting and resist techniques, which can be used with ink jet printing onto textiles. These techniques will display alternative methods for producing high quality customised fabrics

    Combinatorial ink-jet printing for ceramic discovery

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    PhDAn aspirating and dispensing printer established inside a robot gantry equipped with furnace and measurement table is used to prepare thick-film combinatorial libraries. Implementation of series of screening tests for ceramic inks that address stability against sedimentation, evaporation and particle segregation during drying, has provided a series of calibration inks can be used for calibration of this printer. The instrument can assemble ceramic mixtures with compositional accuracy of 1-3 wt %. By changing the amount of dispersant used in the inks or by printing onto a porous substrate, the geometry of residues from dried ceramic ink droplets can be modified to facilitate property measurements and uniform composition, as planned, can be achieved. The same material prepared in three ways, in the form of dried ink, ink-jet printed as for a combinatorial sample and by conventional compaction gave similar dielectric measurements. A combinatorial system has been developed so that combinatorial libraries can be printed, fired and screened automatically. A ternary A1203-TiO2-ZrO2 system was first studied using the developed combinatorial method. The particle segregation during drying of multi-component ceramic ink drops is not due to preferential sedimentation unless dispersant addition is restricted. The segregation is due to the partitioning of particles between the growing peripheral 'foot' that develops during drying and the diminishing liquid pool which contains vigorous recirculation flows. Better dispersed particles remain in the pool and hence are found in excess on the upper surface of residues. Less well dispersed particles join the 'foot' earlier in the drying process. The contact angle and height of droplets containing large amounts of dispersant, steadily reduced during drying until a minimum value was reached; the contact diameter being almost unchanged during drying. These droplet residues retained a dome shape. Droplets of suspensions containing small additions of dispersant terminated in a 'doughnut' shaped residue

    [Pen and Ink Drawings 01]

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    Small, abstract ink drawing.Tiff file: 850x775 pixels, 1.88 Mb; Display: jpeg, 204x186 pixels, 72dp

    [Pen and Ink Drawings 07]

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    Small, abstract ink drawingTiff file: 1131x895 pixels, 2.9 Mb; Display: jpeg, 271x215 pixels, 72dp

    [Pen and Ink Drawings 02]

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    Small, abstract ink drawingTiff file: 1082x800 pixels, 2.48 Mb; Display: jpeg, 206x192 pixels, 72dp

    [Pen and Ink Drawings 03]

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    Small, abstract ink drawingTiff file: 803x972 pixels, 2.23 Mb; Display: jpeg, 193x233 pixels, 72dp
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