196,416 research outputs found
Costituzionalismo africano e global judicial conversation
No full textEditoriale del 12 agosto 2024 di presentazione del Focus Africa di Federalismi.i
Out-of-Equilibrium Clock Model at the Verge of Criticality
No full textWe consider an out-of-equilibrium lattice model consisting of 2D discrete rotators, in contact with heat reservoirs at different temperatures. The equilibrium counterpart of such a model, the clock model, exhibits three phases: a low-temperature ordered phase, a quasiliquid phase, and a high-temperature disordered phase, with two corresponding phase transitions. In the out-of-equilibrium model the simultaneous breaking of spatial symmetry and thermal equilibrium gives rise to directed rotation of the spin variables. In this regime the system behaves as a thermal machine converting heat currents into motion. In order to quantify the susceptibility of the machine to the thermodynamic force driving it out of equilibrium, we introduce and study a dynamical response function. We show that the optimal operational regime for such a thermal machine occurs when the out-of-equilibrium disturbance is applied around the critical temperature at the boundary between the first two phases, namely, where the system is mostly susceptible to external thermodynamic forces and exhibits a sharper transition. We thus argue that critical fluctuations in a system of interacting motors can be exploited to enhance the machine overall dynamic and thermodynamic performances
Energy transfer in molecular devices
No full textProtein machines often exhibit long-range interplay between different sites in order to achieve their biological tasks. We investigate and characterize the nonlinear energy localization and the basic mechanisms of energy transfer in protein devices. By studying two different model protein machines, with different biological functions, we show that genuinely nonlinear phenomena are responsible for energy transport between the different machine sites involved in the biological functions. The energy transfer turns out to be extremely efficient from an energetic point of view: by changing the energy initially provided to the model device, we identify a well defined range of energies where the time for the energy transport to occur is minimal and the amount of transferred energy is a maximum. Furthermore, by introducing an implicit solvent, we show that the energy is localized on the internal residues of the protein structure, thus minimizing the dissipation
Quantum duets working as autonomous thermal motors
No full textWe study the dynamic properties of a thermal autonomous machine made up of two quantum Brownian particles, each of which is in contact with an environment at different temperature and moves on a periodic sinusoidal track. When such tracks are shifted, the center of mass of the system exhibits a nonvanishing velocity, for which we provide an exact expression in the limit of small track undulations. We discuss the role of the broken spatial symmetry in the emergence of directed motion in thermal machines. We then consider the case in which external deterministic forces are applied to the system, and we characterize its steady-state velocity. If the applied external force opposes the system motion, work can be extracted from such a steady-state thermal machine, without any external cyclic protocol. When the two particles are not interacting, our results reduce to those of Fisher and Zwerger [Phys. Rev. B 32, 6190 (1985)PRBMDO0163-182910.1103/PhysRevB.32.6190] and Aslangul, Pottier, and Saint-James [J. Phys. France 48, 1093 (1987)JOPQAG0302-073810.1051/jphys:019870048070109300] for a single particle moving in a periodic tilted potential. We finally use our results for the motor velocity to check the validity of the quantum molecular dynamics algorithm in the nonlinear, nonequilibrium regime
Efficiency fluctuations in steady-state machines
No full textWe study the statistics of the efficiency in a class of isothermal cyclic machines with realistic coupling between the internal degrees of freedom. We derive, under fairly general assumptions, the probability distribution function for the efficiency. We find that the macroscopic efficiency is always equal to the most likely efficiency, and it lies in an interval whose boundaries are universal as they only depend on the input and output thermodynamic forces, and not on the details of the machine. The machine achieves the upper boundary of such an interval only in the limit of tight coupling. Furthermore, we find that the tight coupling limit is a necessary, yet not sufficient, condition for the engine to perform close to the reversible efficiency. The reversible efficiency is the least likely regardless of the coupling strength, in agreement with previous studies. By using a large deviation formalism for the energy currents we derive a fluctuation relation for the efficiency which holds for any number of internal degrees of freedom in the system
Equilibrium Properties and Force-Driven Unfolding Pathways of RNA Molecules
No full textThe mechanical unfolding of a simple RNA hairpin and of a 236-base portion of the Tetrahymena thermophila ribozyme is studied by means of an Ising-like model. Phase diagrams and free energy landscapes are computed exactly and suggest a simple two-state behavior for the hairpin and the presence of intermediate states for the ribozyme. Nonequilibrium simulations give the possible unfolding pathways for the ribozyme, and the dominant pathway corresponds to the experimentally observed one
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