4,026 research outputs found

    Cyberbase Gradignan (documents)

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    Documents et travaux portant sur le corpus “Cyberbase Gradignan

    Cyberbase Gradignan

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    Le corpus 'Cyberbase Gradignan' a été recueilli de juillet 2010 à juin 2012 dans le cadre de l'expérimentation Cyber-base®Justice mise en œuvre la Maison d'Arrêt de Gradignan et finalisée à l'accès à l'information, à l'apprentissage de l'informatique et à l'enseignement. Il est constitué d'enregistrements audiovisuels portant, d'une part, sur les activités dans l'espace informatique de la Maison d'Arrêt et, d'autre part, sur des entretiens avec les différents acteurs. L'ensemble du corpus a d'abord été segmenté et indexé (l'indexation, à la fois contextuelle et thématique, a été reportée dans les noms de fichiers). Une partie des séquences a ensuite été transcrite et annotée

    Cyberbase Gradignan (transcriptions)

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    Transcriptions du corpus 'Cyberbase Gradignan

    Collecting Cures in an Artisanal Manuscript: Practical Therapeutics and Disease in Ms. Fr. 640

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    Scattered throughout Ms. Fr. 640, the forty medical recipes form a small percentage of its over 900 entries. A consideration of the ailments, ingredients, and making processes described in the manuscript, as well as the author-practitioner’s process of collecting information, reveals a variety of connections between Ms. Fr. 640’s medical recipes and early modern artisanal work

    FONDUE-FR-PRINT-16 - Transcriptions of French 16th c. prints

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    <p>HTR Groundtruth for French 16th c. prints, produced with <a href="https://github.com/mittagessen/kraken">Kraken</a> and <a href="https://gitlab.com/scripta/escriptorium">eScriptorium</a>.</p> <p>Original data is available on <a href="https://github.com/FoNDUE-HTR/FONDUE-FR-PRINT-16">GitHub</a>.</p><pre>@misc{FONDUE_FR_PRINT_16, author = {Gabay, Simon}, title = {FONDUE-FR-PRINT-16}, year = {2024},<br> publisher={Zenodo}<br> url={<a href="../doi/10.5281/zenodo.11526149">https://zenodo.org/doi/10.5281/zenodo.11526149</a>}<br> doi={<a href="../doi/10.5281/zenodo.11526149">10.5281/zenodo.11526149</a>}<br>}</pre&gt

    La Palsa Filosofia, o el ateismo, deismo, materialismo, y demas nuevas sectas, convencidas de crimen de estado contra los Soberanos y sus regalias, contra los Magistrados y Potestades legitimas.

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    Book One. Where the vain hypotesis and seditious Principles of Atheists, Deists, Patalists, Naturalists, and other so-called Philosophers are fought. Volume Two. Its author Fr. Fernando de Zevallos, Monge Geronymo of the Monastery of San Isidro del Campo. Second impression. Et nunc Reges intelligire: Erudimini qui judicatis terram. Psalm. 2. v. 10. With privilege and the necessary licenses in Madrid In the Press of Antonio Fernandez. Year of 1775. 1775Book One. Where the vain hypotesis and seditious Principles of Atheists, Deists, Patalists, Naturalists, and other so-called Philosophers are fought. Volume Two. Its author Fr. Fernando de Zevallos, Monge Geronymo of the Monastery of San Isidro del Campo. Second impression. Et nunc Reges intelligire: Erudimini qui judicatis terram. Psalm. 2. v. 10. With privilege and the necessary licenses in Madrid In the Press of Antonio Fernandez. Year of 1775. 177

    Total synthesis of 7-Epi-FR 66979 and 7-Epi-FR 900482

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    The completion of the total synthesis of 7-Epi-FR 66979 and 7-Epi-FR 900482 is presented in this thesis. The natural product FR 66979 and FR 900482 were isolated by the Fujisawa Pharmaceutical Corporation from Streptomyces sandaensis. They are antibiotics with potent antitumor activity. The first stage of the total synthesis is to make indole ester. For the preparation of the precursor of the indole ester, the commercial available starting material 3-hydroxymethylphenol was converted to benzyl aldehyde by using the reagents paraformaldehyde and lewis catalyst SnCl4 after the selective protection of hydroxymethyl group. After the phenol had been protected, this benzyl aldehyde precursor was transformed to indole ester by the Hemetsberger-Knittel reaction in 61% yield. The second stage of the total synthesis is to make fully functionalized pyrroloindole. The indole ester was reduced by DIBAL and then was oxidized to indole aldehyde. The vinylsulfonium salt reacted with this indole aldehyde to form the tetracyclic oxirane, then subsequently treated by sodium azide in acetone-water to afford pyrroloindole in 74% yield. The third stage of the total synthesis is to synthesize the core ring system. The fully functionalized pyrroloindole was successfully oxidized by two equivalents of dimethydioxirane (DMDO) in acetone/water to give ring expanded hydroxylamine hemiketal ring system in 57% yield. The final stage of the total synthesis is to complete the total synthesis. One of the challenging steps is to prepare the hydroxylmethyl group on this core structure. With many studies, the hydrosilylation-oxidation was found to be a good method to make the hydroxymethyl group on this complex molecule. After converting the hydroxymethyl group to urethane and deprotection, 7-Epi-FR 66979 was successfully obtained. With a one step oxidation of 7-Epi-FR 66979, 7-Epi-FR 900482 was prepared. This total synthesis is the shortest and most efficient so far. Epi-FR 66979 is synthesized in 20 steps while epi-FR 900482 required 21 steps. The attempt of making the beta configuration of the hydroxymethyl group on the 7-position for FR 66979 and FR 900482 is also described in this thesis. The efforts included intramolecular hydrosilylation-oxidation, less hindered intermolecular hydrosilylation-oxidation, catalytic hydroboration-oxidation and Danishefsky's methods of the epoxidation and opening. Both less hindered intermolecular hydrosilylation-oxidation and Danishefsky's methods provided intermediate with beta configuration of hydroxymethyl, but the final product was not obtained. A less hindered intermolecular hydrosilylation-oxidation method will provide the best chance to get the natural product when additional more intermediates are prepared in the future.Ph.D.Includes abstractVitaIncludes bibliographical referencesby Weidong Pa

    Effect of CaO content in raw material on the mineral composition of ferric-rich sulfoaluminate clinker

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    Ferric-rich calcium sulfoaluminate (FR-CSA) cement is an eco-friendly cement. Fe2O3 exists in different minerals of FR-CSA clinker, e.g., Ca4Al2Fe2O10 (C4AF), Ca2Fe2O5 (C2F), and Ca4Al6-2xFe2xSO16 (C4A3-xFxS-). The mineral composition depends on the chemical composition of the raw materials and significantly determines the reactivity of FR-CSA cement. To optimize the phase composition of the FR-CSA clinker, chemical reagent raw mixtures with different amounts of CaO were used to prepare the FR-CSA clinker. X-ray diffraction (XRD) analysis, Rietveld quantitative phase analysis (RQPA), Fourier Transform Infrared spectroscopy (FT-IR), and scanning electron microscopy/energy-dispersive spectroscopy (SEM/EDS) were used to identify the mineralogical conditions of the FR-CSA clinker. The results indicated that the amounts of CaO in raw materials greatly affected the iron-bearing phase formation in the FR-CSA clinker. With decreasing CaO content involved in calcination reaction, the amounts of Fe2O3 incorporated in C4A3-xFxS- increased up to 17.72 wt% (where x = 0.36). The findings make it possible to optimize the mineral composition of the FR-CSA clinker by changing the CaO content in raw materials. Furthermore, low CaO content in the raw material is beneficial to the formation of C4A3-xFxS-, which enables the use of solid wastes containing low calcium for producing FR-CSA cement.Accepted author manuscriptMaterials and Environmen

    MULTIPHONIA (MULTImodal database of PHONetics teaching methods in classroom InterActions)

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    Corpus résultant d'enregistrements longitudinaux de cours de correction phonétique en Français Langue Étrangère (FLE) entre avril et juin 2011.Corpus constitué de 96 heures de cours avec des apprenants anglophones de niveaux débutant et intermédiaire, selon deux méthodes de correction phonétique (Méthode Verbo-Tonale et Méthode Articulatoire).Les enregistrements ont été réalisés dans le studio vidéo de la Direction des Technologies de l'Information et de la Communication pour l'Enseignement (DTICE) à l'Université Toulouse II.La durée de chaque cours est de 90 minutes environ

    Patente franciscano confirmando a Fr. Francisco Pareja como custodio de la Florida, 1607 mayo 11

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    Patente que el Padre Comisario General de la Nueva España de los Frailes Menores de San Francisco envió a los frailes de la Custodia de Florida confirmando a Fr. Francisco Pareja como su custodio. —— Patent that the Father General Commissioner of the New Spain of the Friars Minor of San Francisco sent to the friars in the Custody of Florida confirming Fr. Francisco Pareja as custodian. 2 f. (4 p.
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