115 research outputs found
Mixed d-f Block Single-Molecule Toroics
No full textSingle Molecule Toroics pp 15–66Cite as
Mixed d-f Block Single-Molecule Toroics
Keith S. Murray, Stuart K. Langley, Kuduva R. Vignesh, Gopalan Rajaraman, Kieran Hymas & Alessandro Soncini
Chapter
First Online: 24 November 2022
3 Accesses
Abstract
In this chapter, we focus on the single-molecule toroidal (SMT) behaviour of a family of “double dysprosium triangle” heptanuclear species which contain a bridging d-block M(III) or a p-block M(III) ion. They are of general formula [MIIIDyIII 6(OH)8(o-tol)12(NO3)(MeOH)5]∙3MeOH, labelled MDy 6, where o-tol = o-toluate. The parent compound has M = Cr, with subsequent family members having M = Mn, Fe, Co and Al, the latter two having diamagnetic M(III) centres. This heptanuclear family could also be made using chloride as counter-anion rather than nitrate, the molecular structures being similar to the nitrates though the unit cells are different. The LnIII ion could also be varied to include Tb, Ho and Er and, thus, allow exploration of SMT behaviour in non-Dy analogues. The syntheses, structures and magnetic and EPR properties are described, starting with the parent CrDy 6. Theoretical calculations are described in detail, with MOLCAS methods employed to determine anisotropy directions, blocking barriers and relaxation effects and a newly developed model used to calculate magnetically coupled toroidal states and the role of these states in spin dynamics. The direct simulation of the micro-Squid magnetic hysteresis loops of all family members is described as well as that of the original Dy 3 material. Toroido-structural correlations are presented with strategies developed to optimize the important ferrotoroidic coupling between Dy3 triangles in these heptanuclear toroidal species. Finally, we give a brief summary of SMT behaviour in ring-shaped 3d-4f toroidal species
BN SO35 - A Novel Ambulatory Pathway in the Management of Acute Pancreatitis
No full textAcute Pancreatitis (AP) accounts for 20000 admissions per year, resulting in an average hospital stay of 5 days. Over 90% of patient have mild or moderate disease severity. Validated risk stratification tools such as the Harmless Acute Pancreatitis (HAP) score utilised alongside biochemical markers and clinical acumen can predict up to 97% of patients with a mild disease course.
A pathway was introduced at two NHS centres to enable diagnosis and ambulatory management of patients with predicted mild AP with the aim of improving patient experience by preventing unnecessary admission, reducing pressure on surgical departments and providing safe outpatient management
Social Media Response to the Introduction of the Swallowable Gastric Balloon Treatment for Severe Obesity in the NHS: A Snapshot of Public Opinion.
No full textBackground
Swallowable gastric balloons are available in the UK to treat severe obesity. Our hospital introduced this treatment in 2023, the first to do so in the National Health Service (NHS). The event was featured by the British Broadcasting Corporation (BBC) on regional television, in multiple radio interviews, and online by numerous news outlets in February 2024. Obesity and the treatment of obesity are often subject to stigma, prejudice and bias. The event gave an opportunity to observe public opinion in response to a new publicly available obesity treatment.
Methods
Qualitative review of public comments in articles responding to the BBC story about the introduction of swallowable gastric balloon therapy in the NHS. Comments were categorized as positive, neutral, or negative.
Results
Out of 2364 comments reviewed from all sources, 16.6% were positive, 48.9% were neutral and 34.8% were negative. Obesity stigma was highly prevalent in the responses and included many derogatory and abusive comments, including towards the patients featured in the BBC articles.
Conclusions
Obesity stigma is highly prevalent in those responding by social media and on news websites to a new treatment within the NHS. Negative stereotypes may be a barrier to obesity treatment within the NHS and need to be addressed
2010 Seventh International Conference on Information Technology: New Generations
No full textIsaac Macwan (with Hassan Bajwa, Vignesh Veerapandian, and Xinghao Chen) is a contributing author, VHDL Implementation of High-Performance and Dynamically Configures Multi-port Cache Memory, pp. 1212-1216.https://digitalcommons.fairfield.edu/engineering-books/1057/thumbnail.jp
How the planning, engineering and politics of transportation established, preserves and perpetuates the automobile city
No full textThesis (M.C.P.)--Massachusetts Institute of Technology, Dept. of Urban Studies and Planning; and, (S.M. in Transportation)--Massachusetts Institute of Technology, Dept. of Civil and Environmental Engineering, 2012.This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.Cataloged from student submitted PDF version of thesis. Page [167] blank.Includes bibliographical references (p. 161-166).The last eight decades of urban transportation planning and engineering in the United States have been dominated by the hegemony of the automobile. Auto-oriented planning of the transportation and land use system has had a profound impact on the built environment both in greenfield developments and neighborhoods that predated the auto. The pedestrian quality of cities has been eroded by the automobile, and urban renewal in the United States erased many neighborhoods strongly oriented around walking and transit use. Equally pervasive as the auto itself is the place for the car in the institutional cultures and practices involved in shaping the city. The shortcomings of mobility-oriented transportation planning have been well critiqued, even from the very early days of Interstate building. In recent decades there has been a flurry of interest in articulating sustainable transportation policies to provide multi-modal accessibility and to consider the interactions between transportation, land use, and other policy realms such as health, energy, environment and equity. The current impending crisis of aging and ailing highway structures in the United States presents a momentous opportunity to reassess the need and purpose of such infrastructure, and to rebuild, reconceptualize, or remove it in a matter more consistent with current policy goals and planning processes - rather than the ones in place when initially built. Despite the interest, need and opportunity to reconceptualize aging infrastructure in America to support a more sustainable reshaping of land use and activity patterns, the potential to do so is heavily impaired by a transportation planning process that is still dominated by the tools, methods and assumptions, political biases, procedural failures, and instilled human behaviors of the first highway-building era. The McGrath Highway in Somerville, MA is used as a case study to discuss how persistence of 1950s technical, procedural and political dysfunctions threaten to undermine this opportunity. Short-term actions and strategies to avoid this impending fate are suggested for McGrath Highway with applicability to a wider national context of similar opportunities.by Vignesh Krishnamurthy.S.M.in TransportationM.C.P
In-Situ Infrared Spectroscopic Studies of Palladium Thin Films during CO2 Electro-Reduction
No full textAn exponential growth in CO2 concentration over the past few decades has led to an accelerated impact of climate change on planet earth. In a bid to curb these emissions, people across the globe are slowly transitioning towards renewable energy sources with battery technology aiding this growth. Given that battery technology is still in its nascent stage, the “Electrochemical reduction of CO2” could be a viable solution supporting it without decelerating the momentum gained towards renewable development. Although plausible, the direct reduction of CO2 to liquid fuels entails huge energy expenditure thus requiring the implementation of catalysts. Unique in its ability, palladium reversibly reduces CO2 to formic acid making it an interesting candidate for the reduction reaction. In addition to the production of formic acid, palladium is also know to produce carbon monoxide (CO) which completely deactivates the surface preventing further reactions from occurring. Thus the aim of the current study is focused on analysing the electrochemical reduction of CO2 on palladium thin films using surface enhanced infrared absorption spectroscopy to better understand the deactivation mechanisms of CO on the palladium thin film. The smoothness of the as- sputtered 15 nm palladium thin film with a RMS roughness of 0.511 nm and partially coalesced islands were ascertained, thus requiring surface activation to introduce the enhancement mechanism. Experimental analysis of CO2 reduction on the palladium thin film was performed to unearth significant insights through the combination of electrochemical analysis techniques with surface enhanced infrared absorption spectroscopy. Results obtained through implementation of these methodologies provided substantial information not only on the influence of the palladium-hydrogen system on the electrochemical reduction of CO2 but also on the impact of alkali metal cations on the palladium-hydrogen system and the CO2 reduction reaction over the sputtered palladium thin film. CO formation, accumulation and desorption coupled with hydrogen evolution and desorption were some of the few avenues that were enumerated upon during the experimental investigation. The identity of CO chemisorbed on the palladium thin film along with bicarbonate direct/ indirect reduction to form CO was confirmed through the utilization of N2 saturated C13 NaHCO3 solution. In addition to the analysis of the reduction reaction, emphasis on the oxidation of CO was also provided suggesting the formation of dense CO structures with the existence of strong CO dipole – dipole coupling on the palladium surface. Materials Science and Engineerin
Stability of excitons in double quantum well: Through electron and holes transmission probabilities
No full textEffect of non-parabolicity and confinement potential on exciton binding energy in a quantum well
No full textWAAM Martensitic Stainless Steel: Process Optimization & Resulting Weld Geometrical Characterization
No full textWire Arc Additive Manufacturing (WAAM), one of the Additive Manufacturing (AM) deposition methods which employs the basic principles of Gas Metal Arc Welding (GMAW) welding technique was used to show that it is possible to build moulds for ceramic products using AISI 420 stainless steel due to its characteristics such as corrosion resistance, machinability, hardness and dimensional stability. The WAAM process also is efficient in terms of its deposition rate, reduced material wastage and high surface quality.To investigate the feasibility of AM of AISI 420 stainless steel using WAAM, Response Surface Methodology (RSM - a predictive technique) was used to navigate within the input parameter range for process optimization. Bead-on-plate welding experiments were performed with a MIG welding robot on a structural steel (S355J2) as the substrate. In the tested range according to RSM analyses, the optimum weld condition was 261 A (Current), 29 V (Volts) and 0.59 m/min S (Travel Speed) with preheating at 200°C. However, this condition was found to be unsuitable for AM due to its low deposition speed, non - uniform building surface morphology and inter-run porosities when overlapping welds were deposited. Further analyses on the metallurgy of the WAAM AISI 420 stainless steel through Scanning Electron Microscope (SEM) revealed that the weld metal consisted of a martensite matrix and delta-ferrite at the grain boundaries. The Vickers Hardness of the weld metal was 514HV.To achieve WAAM feasibility using AISI 420 stainless steel, modified RSM method was performed by expanding the input parameters and visually inspecting the bead for its shape, size and quality. The experiment adopted was called the Ramping Procedure wherein a single resulting weld bead can represent many input parameter combinations. The optimum condition for the input parameters were identified to be 200 A (Current), 18.5 V (Volts) and 1.00 m/min S (Travel Speed). With the optimal processing conditions, rectangular blocks or walls were modelled and designed in the Autodesk Powermill software and built to evaluate the feasibility of WAAM AISI 420 stainless steel. Samples were built without preheating and no surface defects and cracking were observed. Microstructural and hardness studies were then performed. Results show that the as-welded weld metal consisted of delta-ferrite present in a martensite matrix. The hardness of the weld metal was 623 HV. The WAAM optimization procedure for AISI 420 stainless steel that has not been explored for AM processes due to its high sensitivity to welding thermal cycles that can lead to cracking. In this study, it has been successfully demonstrated that crack free AISI 420 stainless steel can be deposited with WAAM
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