1,721,137 research outputs found
Poly-chlorinated dibenzo-p-dioxins, dibenzo-furans and dioxin-like poly-chlorinated biphenyls occurrence and removal in conventional and membrane activated sludge processes
The paper presents the results of a study focused on the occurrence and removal of dioxins and furans (PCDD/F) and poly-chlorinated biphenyls (PCB) in both conventional and membrane wastewater treatment processes. It was found that the conventionally activated sludge process could perform a good removal of PCDDs/Fs and PCBs, but the relatively low solid retention time applied and the presence of suspended solids in the effluent limited the removal capability of the system. On the other hand, the membrane bioreactor was capable of perfectly removing PCDDs/Fs and PCBs giving an effluent characterised by concentrations under the limit of detection for most of the tested compounds. This efficiency was the result of both the solids removal from the effluent (permeate) and the application of prolonged solid retention times which enabled the bioconversion of those compounds as demonstrated by the mass balances. A mathematical model was developed to predict the final fate of a given molecule according to the operational conditions applied in the wastewater treatment process.<br/
Nutrients recovery from anaerobic digestate of agro-waste: Techno-economic assessment of full scale applications
The sustainable production of fertilizers, especially those based on phosphorus, will be one of the challenges of this century. Organic wastes produced by the agriculture, urban and industrial sectors are rich in nutrients which can be conveniently recovered and used as fertilizers. In this study five full scale systems for the recovery of nutrients from anaerobic digestate produced in farm-scale plants were studied. Monitored technologies were: drying with acidic recovery, stripping with acidic recovery and membrane separation. Results showed good performances in terms of nutrients recovery with average yields always over 50% for both nitrogen and phosphorus. The techno-economic assessment showed how the specificity of the monitored systems played a major role: in particular, membranes were able to produce a stream of virtually pure water (up to 50% of the treated digestate) reducing the digestate volume, while drying, because of the limitation on recoverable heat, could treat only a limited portion (lower than 50%) of produced digestate while stripping suffered some problems because of the presence of suspended solids in the liquid fraction treated. Specific capital and operational costs for the three systems were comparable ranging between 5.40 and 6.97 € per m3 of digestate treated and followed the order stripping > drying > membranes. Costs determined in this study were similar to those observed in other European experiences reported in literature
Exploring the potential of membrane bioreactors to enhance metals removal from wastewater: pilot experiences.
Nutrients recovery from anaerobic digestate of agro-waste: Techno-economic assessment of full scale applications
The sustainable production of fertilizers, especially those based on phosphorus, will be one of the challenges of this century. Organic wastes produced by the agriculture, urban and industrial sectors are rich in nutrients which can be conveniently recovered and used as fertilizers. In this study five full scale systems for the recovery of nutrients from anaerobic digestate produced in farm-scale plants were studied. Monitored technologies were: drying with acidic recovery, stripping with acidic recovery and membrane separation. Results showed good performances in terms of nutrients recovery with average yields always over 50% for both nitrogen and phosphorus. The techno-economic assessment showed how the specificity of the monitored systems played a major role: in particular, membranes were able to produce a stream of virtually pure water (up to 50% of the treated digestate) reducing the digestate volume, while drying, because of the limitation on recoverable heat, could treat only a limited portion (lower than 50%) of produced digestate while stripping suffered some problems because of the presence of suspended solids in the liquid fraction treated. Specific capital and operational costs for the three systems were comparable ranging between 5.40 and 6.97 € per m3 of digestate treated and followed the order stripping > drying > membranes. Costs determined in this study were similar to those observed in other European experiences reported in literature
A Multiproduct Biorefinery Approach for the Production of Hydrogen, Methane and Volatile Fatty Acids from Agricultural Waste
A pilot scale biorefinery platform for the treatment of agro-waste and the production of hydrogen, methane and volatile fatty acids was studied in real environment. The system adopted was a two stage anaerobic process where hydrogen and volatile fatty acids were produced in the first phase (fermentation) and methane in the second one (digestion). The study demonstrated the possibility to produce a biogas composed by hydrogen and methane (10% and 55%, respectively) while recovering volatile fatty acids. The yield for acids production was equivalent to 0.13 gVFA/gTVS (as COD) with acetate and butyrate as dominant observed species.Graphic Abstract[GRAPHICS]
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