1,721,032 research outputs found

    Black Carbon in Deep-Sea Sediments

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    Lipid-like material as the source of the uncharacterized organic carbon in the ocean?

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    The composition and formation mechanisms of the uncharacterized fraction of oceanic particulate organic carbon (POC) are not well understood. We isolated biologically important compound classes and the acid-insoluble fraction, a proxy of the uncharacterized fraction, from sinking POC in the deep Northeast Pacific and measured carbon isotope ratios to constrain the source(s) of the uncharacterized fraction. Stable carbon and radiocarbon isotope signatures of the acid-insoluble fraction were similar to those of the lipid fraction, implying that the acid-insoluble fraction might be composed of selectively accumulated lipid-like macromolecules.X1155sciescopu

    Blank correction for Delta C-14 measurements in organic compound classes of oceanic particulate matter

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    Contaminant carbon (blank carbon) was studied for its impact on the carbon isotope measurements (Delta C-14 and delta C-13) of 3 organic compound classes of oceanic particulate organic matter. Two methods of blank correction and associated uncertainties were studied. First, the carbon blanks were quantified manometrically and the isotope ratios of the blank carbon were measured directly. Second, the isotope ratios of the blank carbon were estimated using the standard dilution method from the difference in Delta C-14 values between unprocessed and processed standards. The 2 methods agreed within the uncertainties. The standard deviations of numerous Delta C-14 measurements made on processed standard compounds were comparable to those of real samples. Blank correction using the standard dilution method is much less sensitive to the error in determination of blank carbon mass than is correction using the directly measured mass and Delta C-14 values of the blank carbon. The standard dilution method is recommended for correcting Delta C-14 analyses of small samples that involve incorporation of a significant amount of blank carbon.X1119sciescopu

    Carbon isotope ratios of organic compound fractions in oceanic suspended particles

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    To study cycling of organic fractions in the ocean, relative abundances and radio- and stable-carbon isotope measurements of total lipid extract, acid-soluble, and acid-insoluble fractions of suspended particulate organic carbon (POC) were made. Changes in relative abundances occurred mostly in the upper 1000 m of the water column, with a decrease in total lipid extract and the acid-soluble fraction and an increase in the acid-insoluble fraction with increasing depth. We found lower Delta(14)C values for total lipid extract and the acid-insoluble fraction than for the acid-soluble fraction, which is consistent with the previous suggestion of incorporation of dissolved organic carbon and/or resuspended sediment to POC (Druffel and Williams, 1990; Sherrell et al., 1998). The Delta(14)C values of these fractions in a given organic carbon pool must be understood in terms of acquisition of (14)C-depleted carbon from other carbon pools in addition to aging within the reservoir.X1113sciescopu
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