3 research outputs found
Metal sulfide-based nanomaterials for electrochemical CO<sub>2</sub> reduction
No full textThe electrochemical CO2 reduction (ECO2R) is critical to enabling the widespread use of abundant renewable energy sources. However, in order to successfully implement such technologies on an industrial scale, necessary advancement in both the material and molecular design of electrocatalysts is required. In recent years, metal-sulfide (MS)-based nanomaterials have been explored as promising electrocatalysts for ECO2R. This article provides a systematic review of the design and development of MS-based catalysts for ECO2R, including their synthesis, characterization, reaction mechanism, catalytic performance, and strategies for future optimization. The current state-of-the-art MS-based ECO2R catalysts and their technical challenges are outlined herein with the purpose of establishing new guidelines for the rational design of next generation MS-based catalysts for CO2 electroreduction.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.ChemE/Materials for Energy Conversion and Storag
Living with Floods Using State-of-the-Art and Geospatial Techniques: Flood Mitigation Alternatives, Management Measures, and Policy Recommendations
No full textFlood, a distinctive natural calamity, has occurred more frequently in the last few decades all over the world, which is often an unexpected and inevitable natural hazard, but the losses and damages can be managed and controlled by adopting effective measures. In recent times, flood hazard susceptibility mapping has become a prime concern in minimizing the worst impact of this global threat; but the nonlinear relationship between several flood causative factors and the dynamicity of risk levels makes it complicated and confronted with substantial challenges to reliable assessment. Therefore, we have considered SVM, RF, and ANN—three distinctive ML algorithms in the GIS platform—to delineate the flood hazard risk zones of the subtropical Kangsabati river basin, West Bengal, India; which experienced frequent flood events because of intense rainfall throughout the monsoon season. In our study, all adopted ML algorithms are more efficient in solving all the non-linear problems in flood hazard risk assessment; multi-collinearity analysis and Pearson’s correlation coefficient techniques have been used to identify the collinearity issues among all fifteen adopted flood causative factors. In this research, the predicted results are evaluated through six prominent and reliable statistical (“AUC-ROC, specificity, sensitivity, PPV, NPV, F-score”) and one graphical (Taylor diagram) technique and shows that ANN is the most reliable modeling approach followed by RF and SVM models. The values of AUC in the ANN model for the training and validation datasets are 0.901 and 0.891, respectively. The derived result states that about 7.54% and 10.41% of areas accordingly lie under the high and extremely high flood danger risk zones. Thus, this study can help the decision-makers in constructing the proper strategy at the regional and national levels to mitigate the flood hazard in a particular region. This type of information may be helpful to the various authorities to implement this outcome in various spheres of decision making. Apart from this, future researchers are also able to conduct their research byconsidering this methodology in flood susceptibility assessment
Source identification and potential health risks from elevated groundwater nitrate contamination in Sundarbans coastal aquifers, India
No full textAbstract In recent years groundwater contamination through nitrate contamination has increased rapidly in the managementof water research. In our study, fourteen nitrate conditioning factors were used, and multi-collinearity analysis is done. Among all variables, pH is crucial and ranked one, with a value of 0.77, which controls the nitrate concentration in the coastal aquifer in South 24 Parganas. The second important factor is Cl−, the value of which is 0.71. Other factors like—As, F−, EC and Mg2+ ranked third, fourth and fifth position, and their value are 0.69, 0.69, 0.67 and 0.55, respectively. Due to contaminated water, people of this district are suffering from several diseases like kidney damage (around 60%), liver (about 40%), low pressure due to salinity, fever, and headache. The applied method is for other regions to determine the nitrate concentration predictions and for the justifiable alterationof some management strategies
