1,720,963 research outputs found
Sintesi e Caratterizzazione Spettroscopica e Strutturale delle Differenti Configurazione del Legante Amminico Tridentato N,N?,N?-trimetildietilenetriammina Coordinato al Platino
No full textBis Deprotonation of a Platinum(II)-Bonded Propene Affords an Unprecedended eta1,eta3-Allyl Moiety Bridging Two Metal Centers
No full textSynthesis and Structural characterization of the tridentate amine ligand N,N?,N?-trimethyldiethylenetriamine coordinated to platinum
No full textMarkovnikov versus anti-Markovnikov selectivity in the amination of terminal olefins coordinated to platinum(II)
No full textAiding Factors in the Formation of Azaplatinacyclobutane Rings – X-ray and Crystal Structure of [Pt{CH(Ph)CH2NEt2-κC,κN}(N,N,N′,N′-tetramethylethylenediamine)]+ and of Its Open-Chain Precursor
No full textVynilic Deprotonation in the Coordination Sphere of Platinum(II): Regioselective Formation of Alkenyl Complexes
No full textRole of metal ions and hydrogen bond acceptors in the tautomeric equilibrium of nitro-9[(alkylamino)amino]-acridine drugs
No full textBis deprotonation of a platinum(II)-bonded propene affords an unprecedented eta1, eta3-allyl moiety bridging two metal centers
No full textThe conversion of a eta (2)-bonded propene (complex 1) into a bridging eta (1),eta (3)-allyl moiety (complex 4) is reported. The formation of 4 occurs through the following sequence of reactions: deprotonation of the methyl group of the coordinated propene in 1 and formation of the eta (1)-allyl complex 2, displacement of the eta (2)-olefin of a second molecule of 1 by the eta (1)-allyl moiety of 2 and formation of the eta (1),eta (2)-allyl-bridged dinuclear complex 3, and finally further deprotonation of the eta (1)-bonded methylene group of 3 and simultaneous release of a chloride ion by one platinum unit leading to formation of the eta (1),eta (3)-allyl-bridged platinum dimer 4
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