16 research outputs found

    Complexities of Contact Potential Difference Measurements on Metal Halide Perovskite Surfaces

    No full text
    Understanding the stability of metal halide perovskite (MHP) surfaces is of considerable interest for the development of devices based on these materials. We present here a vacuum-based study of the surface potential and response to illumination of two different types of perovskite films, methylammonium lead bromide (MAPbBr3) and the 2D Ruddlesden–Popper phase butylammonium lead iodide (BA2PbI4, n = 1), using Kelvin probe-based contact potential difference and surface photovoltage measurements. We show that supraband gap light irradiation can induce the loss of halide species, which adsorb on the Kelvin probe tip, inducing quasi-irreversible changes of the MHP surface and tip work functions. If undetected, this can lead to misinterpretations of the MHP surface potential. Our results illustrate the effectiveness of the Kelvin probe-based technique in providing complementary information on the energetics of perovskite surfaces and the necessity to monitor the work function of the probe to avoid erroneous conclusions when working on these materials

    Birth weight and risk of Type 2 diabetes: a quantitative systematic review of published evidence

    No full text
    Birth weight and risk of Type 2 diabetes: a quantitative systematic review of published evidenc

    Birth weight and risk of type 2 diabetes: A quantitative systematic review of published evidence

    No full text
    Birth weight and risk of type 2 diabetes: A quantitative systematic review of published evidenc

    Temperature effects on metabolic rate and cardiorespiratory physiology of the spiny rock lobster (Jasus edwardsii) during rest, emersion and recovery

    No full text
    Temperature effects on metabolic rate and cardiorespiratory physiology of the spiny rock lobster (Jasus edwardsii) during rest, emersion and recover

    Birth weight and risk of type 2 diabetes: A quantitative systematic review of published evidence

    No full text
    Birth weight and risk of type 2 diabetes: A quantitative systematic review of published evidenc

    Birth weight and risk of Type 2 diabetes: a quantitative systematic review of published evidence

    No full text
    Birth weight and risk of Type 2 diabetes: a quantitative systematic review of published evidenc

    Navigating the future: Strategic management of a mobile aquaculture system with receding-horizon control

    No full text
    The New Zealand-based Whakapohewa ki ahumoana Reimagining Aquaculture project (funded by the Ministry for Business, Innovation and Employment Endeavour Fund) lead by Plant & Food Research, is designing a mobile aquaculture system for finfish, towed by an autonomous vessel, powered by renewable energy sources. This work presents the vessel management strategy for this mobile aquaculture solution, inspired by receding-horizon control, which uses available weather forecasts to minimize the energy consumption by the autonomous vessel while maintaining an optimal flow speed through the fish enclosure such that the optimal biological conditions (e.g. swim speed) for the fish can be maintained. The simulations performed for a generalized salmonid fish species cultured in Tasman Bay, New Zealand show that the food storage capacity of the autonomous vessel is consistently a limiting factor at low swim speeds (≤ 0.4 m s−1), while energy capacity limits at higher swim speeds. The simulations highlight how such a strategy allows the system to successfully shelter from storms and by virtue of going further from its “safe haven” can maintain optimal conditions for the fish through the enclosure. We anticipate this work to be a starting point for more sophisticated management strategies considering engineering criteria, species specific requirements, and environmental parameters such as temperature and water quality that impact fish welfare explicitly

    Are noise and air pollution related to the incidence of dementia? A cohort study in London, England.

    No full text
    OBJECTIVE: To investigate whether the incidence of dementia is related to residential levels of air and noise pollution in London. DESIGN: Retrospective cohort study using primary care data. SETTING: 75 Greater London practices. PARTICIPANTS: 130 978 adults aged 50-79 years registered with their general practices on 1 January 2005, with no recorded history of dementia or care home residence. PRIMARY AND SECONDARY OUTCOME MEASURES: A first recorded diagnosis of dementia and, where specified, subgroups of Alzheimer's disease and vascular dementia during 2005-2013. The average annual concentrations during 2004 of nitrogen dioxide (NO2), particulate matter with a median aerodynamic diameter ≤2.5 µm (PM2.5) and ozone (O3) were estimated at 20×20 m resolution from dispersion models. Traffic intensity, distance from major road and night-time noise levels (Lnight) were estimated at the postcode level. All exposure measures were linked anonymously to clinical data via residential postcode. HRs from Cox models were adjusted for age, sex, ethnicity, smoking and body mass index, with further adjustments explored for area deprivation and comorbidity. RESULTS: 2181 subjects (1.7%) received an incident diagnosis of dementia (39% mentioning Alzheimer's disease, 29% vascular dementia). There was a positive exposure response relationship between dementia and all measures of air pollution except O3, which was not readily explained by further adjustment. Adults living in areas with the highest fifth of NO2 concentration (>41.5 µg/m3) versus the lowest fifth (<31.9 µg/m3) were at a higher risk of dementia (HR=1.40, 95% CI 1.12 to 1.74). Increases in dementia risk were also observed with PM2.5, PM2.5 specifically from primary traffic sources only and Lnight, but only NO2 and PM2.5 remained statistically significant in multipollutant models. Associations were more consistent for Alzheimer's disease than vascular dementia. CONCLUSIONS: We have found evidence of a positive association between residential levels of air pollution across London and being diagnosed with dementia, which is unexplained by known confounding factors
    corecore