45 research outputs found
Trends in high sea levels of German North Sea gauges compared to regional mean sea level changes
No full textThe impacts of rising mean sea levels will be felt most acutely during periods of extreme high sea levels which are caused by the combination of mean sea level, tides and storm surges. In this paper, we examine sea level records from six tide gauges along the German North Sea coastline to determine if changes in high sea levels observed throughout the 20th century and early 21st century were primarily driven by increases in mean sea level (i.e. like what has been observed by other authors in most parts of the world) or whether other factors, such as changes in ocean tides or storm surges also contributed significantly to observed changes in high water in this region. Time-series of annual 80th, 85th, 90th, 95th, 99th, and 99.9th percentiles are derived from the sea level records and trends are assessed using linear regression for the entire time periods for which datasets are available at each site and for the common period from 1953 to 2008. The percentile time-series are subsequently reduced relative to mean sea level and a second set of trends are estimated. At all sites and percentile levels, significant positive trends are evident for the observed sea level data. Once the percentile time-series are reduced relative to mean sea level the remaining trends are still significant at the 1?-confidence level, with the exception of the 99.9th percentiles since the standard errors are large. Using a non-linear trend analysis, on the long Cuxhaven record, we find that prior to the mid-1950s and from about 1990 onwards, changes in high sea levels were not different from mean sea level changes. However, from the mid-1950s to 1990 changes were significantly different from those observed in mean sea level. Possible reasons for this appear to be due to changes in the amplitudes of several main tidal constituents, which are apparent since the mid-1950s and decadal variability in the storm activity (with strong westerly winds in the North Atlantic region from 1960 to the 1990s)
Influence of the Recirculation of Various by-products Generated through Electric Arc Furnace Route on EAF Slag Quality
No full textThe Fines2EAF project aims to increase the value of Electric Arc Furnace steelmaking residues by their internal recycling and reuse in form of cement-free briquettes. The project sustainability for a profitable fines' recirculation pass through the conservation of steel and slag quality in terms of chemistry, physics and eco friendliness. To do this, industrial trials have been conducted by the charging of self-reducing and slag-former briquettes made by primary and secondary fines materials. Several slag samples supplied from three different European EAF steel shops have been analysed. The specimens have been characterized by XRF, XRD and SEM to thoroughly define their crystallography, morphology and microstructure. The comparison with the corresponding reference samples (i.e., slag produced without the fines recirculation) also allowed to highlight the differences present. Leaching tests have been conducted on reference and briquette- added slag according to EN 12457-4 standard to assess the compliant with the local environmental regulation. The obtained results highlighted that the slag obtained using cement-free briquettes made by steelmaking fines exhibits crystallographic and morphological properties very similar to the reference samples, with limited differences attributed to slag and scrap feedstock intrinsic heterogeneity. No relevant increase in the leachate concentration could be detected when compared to reference samples and the influence of raw-material fines recirculation into the EAF could be considered at worst negligible, if not positive for some elements like Ba ( - 22.86%), V ( - 13.19%) and W ( - 14.83%). Considering all the analyses performed, no adverse effect on slag quality could be detected
Investigation of (BOF) converter slag use for agriculture in Europe
No full textThe goal of zero-waste is one of the main challenges of modern steel industry, which over the past 20 years has been committed to increase the recovery and the use of by-products generated during the ironmaking and steelmaking processes. Among the main by-products generated during iron and steel production, such as slags, dusts and sludges, slags constitute about 90% of the total. Slags are currently used in various fields (such as cement production, road construction, environmental recovery in landfill covers, as fertilizer and soil conditioner, etc.) according to their chemical features, which depend on production process origin. In Italy, in particular for example, BF (Blast Furnace) slag is used for cement production while BOF (Basic Oxygen Furnace) slag without iron (inert slag) is used as landfill cover, in compliance with Italian legislation. In Germany, BF and BOF slag use as fertlisers and liming materials has a long tradition. Although in recent years slag use has increased, the application for agriculture purposes needs to be further investigated. Slag can be used as a soil conditioner (high content of Ca and Mg), Si supply (improves the crops resistance to pests and diseases), P fertilizer production and micro-nutrients supply. Use of slags can affect human health and environment, because of heavy metal content, which can leache to groundwater or be transferred to surface water. The assessment of risk to the environment based on slag application requires further investigation. This represents an opportunity for both the steel and fertilizer industries to promote natural resources savings, CO2 emission reductions, landfill waste prevention as well as social awareness of sustainability of some industrial activities. The BOF slag has been shown to be useful as liming material for acidic soil amendment and it can replace commercial fertilizers. Different effects on crop yields and on soil parameters can be found, depending on soil characteristics and climate conditions. In Middle Europe, with humid climate, lime losses through leaching of up to 0.5 t CaO/ha have to be replaced with liming material to prevent acidification. Evaluation of long-term field trials with slag liming materials can give information about the impact of slag applications on crop management and the environment. In Mediterranean regions, such as in Italy, arable soils rarely show acidic characteristics. Alkaline soils from coastal areas are often rich in sodium content, due to seawater intrusion and irrigation with saline water. The aim of this research is also to investigate the application of BOF slag to these soils, in order to assess the effect of Ca contained in slag in balancing negative Na effects. This paper is based on the preliminary study and experiments carried out within an ongoing RFCS (Research Fund for Coal and Steel) project
Investigation of (BOF) Converter slag use for agriculture in Europe
No full textThe goal of zero-waste is one of the main challenges of modern steel industry, which over the past 20 years has been committed to increase the recovery and the use of by-products generated during the ironmaking and steelmaking processes. Among the main by-products generated during iron and steel production, such as slags, dusts and sludges, slags constitute about 90% of the total. Slags are currently used in various fields (such as cement production, road construction, environmental recovery in landfill covers, as fertilizer and soil conditioner, etc.) according to their chemical features, which depend on production process origin. In Italy, in particular for example, BF (Blast Furnace) slag is used for cement production while BOF (Basic Oxygen Furnace) slag without iron (inert slag) is used as landfill cover, in compliance with Italian legislation. In Germany, BF and BOF slag use as fertlisers and liming materials has a long tradition. Although in recent years slag use has increased, the application for agriculture purposes needs to be further investigated. Slag can be used as a soil conditioner (high content of Ca and Mg), Si supply (improves the crops resistance to pests and diseases), P fertilizer production and micro-nutrients supply. Use of slags can affect human health and environment, because of heavy metal content, which can leache to groundwater or be transferred to surface water. The assessment of risk to the environment based on slag application requires further investigation. This represents an opportunity for both the steel and fertilizer industries to promote natural resources savings, CO2 emission reductions, landfill waste prevention as well as social awareness of sustainability of some industrial activities. The BOF slag has been shown to be useful as liming material for acidic soil amendment and it can replace commercial fertilizers. Different effects on crop yields and on soil parameters can be found, depending on soil characteristics and climate conditions. In Middle Europe, with humid climate, lime losses through leaching of up to 0.5 t CaO/ha have to be replaced with liming material to prevent acidification. Evaluation of long-term field trials with slag liming materials can give information about the impact of slag applications on crop management and the environment. In Mediterranean regions, such as in Italy, arable soils rarely show acidic characteristics. Alkaline soils from coastal areas are often rich in sodium content, due to seawater intrusion and irrigation with saline water. The aim of this research is also to investigate the application of BOF slag to these soils, in order to assess the effect of Ca contained in slag in balancing negative Na effects. This paper is based on the preliminary study and experiments carried out within an ongoing RFCS (Research Fund for Coal and Steel) project
Developing a new process to agglomerate secondary raw material fines for recycling in the electric arc furnace - The fines2EAF project
No full textRecent years have seen a worldwide change in the environmental policy towards circular economy approaches. It is estimated that steel-making activities in Europe produce about 80 million tonnes annually of by-products and waste, equivalent to half of the European steel production, of which more than 10 million tonnes is waste for disposal. This waste of resources and land area is not sustainable and has to be decreased in the future. The Fines2EAF project aims to increase the value of steelmaking residues by internal recycling and (re)use in the form of agglomerates. The benefit of this strategy is threefold: improved utilization of residues, internal recovery of valuable materials and reduction of the amount of dumped materials. The approach followed is the development of an innovative process to produce cement-free agglomerates based on primary and secondary raw material fines, alternative binder systems and a hydraulic stamp press. In addition, a new pre-treatment process for fines based on microwave heating is investigated. The first results of the lab-scale investigation of the fines pre-treatment to reduce the amount of zinc, volatiles and alkalis are presented. Six materials from two steel plants have been tested in a laboratory microwave furnace. Also presented are first results of the agglomeration of fines using a laboratory press
Developing a new process to agglomerate secondary raw material fines for recycling in the electric arc furnace - the Fines2EAF project
No full textRecent years have seen a worldwide change in the environmental policy towards circular economy approaches. It is estimated that steel-making activities in Europe produce about 80 million tonnes annually of by-products and waste, equivalent to half of the European steel production, of which more than 10 million tonnes is waste for disposal. This waste of resources and land area is not sustainable and has to be decreased in the future. The Fines2EAF project aims to increase the value of steelmaking residues by internal recycling and (re)use in the form of agglomerates. The benefit of this strategy is threefold: improved utilization of residues, internal recovery of valuable materials and reduction of the amount of dumped materials. The approach followed is the development of an innovative process to produce cement -free agglomerates based on primary and secondary raw material fines, alternative binder systems and a hydraulic stamp press. In addition, a new pre-treatment process for fines based on microwave heating is investigated. The first results of the lab-scale investigation of the fines pre-treatment to reduce the amount of zinc, volatiles and alkalis are presented. Six materials from two steel plants have been tested in a laboratory microwave furnace. Also presented are first results of the agglomeration of fines using a laboratory press
Impact of long-term application of blast furnace and steel slags as liming materials on soil fertility and crop yields
No full textMUSE Modellgestützte Untersuchungen zu Sturmfluten mit geringen Eintrittswahrscheinlichkeiten - Teil D: Statistisch-probalistische Extremwertanalyse
No full textKFKI-Projekt: MUSE. BMBF-Fördernummer: 03KIS039A, 03KIS039B, 03KIS039
