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    Vanadyl(IV) - Acetate Complexes in Aqueous Solution.

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    The formation of vanadyl(IV) complexes with acetates were studied by potentiometric titrn. methods; the stepwise formation consts. of mononuclear complexes, [VO(CH3COO)]+ and [VO(CH3COO)2], were calcd. to be 72.2 and 12.6 M-1, resp., in 1 M aq. perchlorate at 25 °C. A comparison was made with the literature values for the corresponding neptunyl(IV) complexes

    Vanadyl(IV) - Monocarboxylate Complexes in Aqueous Solution.

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    The complex formation of vanadyl(IV) with monochloroacetate, β-chloropropionate and glycolate ions was studied by potentiometric [H+] measurements in 1 M NaClO4 soln. at 25 °C. The VO2+ ion forms mononuclear successive complexes with a coordination no. > 2. The relationship between the stability of the vanadyl complexes and the ligand basicity is discussed
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