56,048 research outputs found
Papers from the British Academy Lucy to Language: Archaeology of the Social Brain. Seminar Series on Palaeolithic Visual Display.
ContentsThe Importance of Conveying Visual Information in Acheulean Society. The Background to the Visual Display HypothesisDr John McNabb, Centre for the Archaeology of Human Origins (CAHO), Department of Archaeology, University of Southampton, Southampton, Hampshire, SO17 1BF, [email protected] Identity Model: a theory to access visual display and hominin cognition within the PalaeolithicJames Cole, Centre for the Archaeology of Human Origins (CAHO), Department of Archaeology, University of Southampton, Southampton, Hampshire, SO17 1BF, [email protected] Tool Production, Neural Integration and the Social BrainDerek Hodgson, Department of Archaeology, University of York, York, [email protected] Phylogeny and Ontogeny in Hominin Brain EvolutionFiona Coward, Department of Geography Royal Holloway University of London, Egham, Surrey, TW20 0EX, [email protected] Grove, School of Archaeology, Classics and Egyptology, University of Liverpool, G.09 HartleyBuilding, Brownlow Street, Liverpool L69 3GS, [email protected]
Climate change and ocean acidification impacts on lower trophic levels and the export of organic carbon to the deep ocean
Most future projections forecast significant and ongoing climate change during the 21st century, but with the severity of impacts dependent on efforts to restrain or reorganise human activity to limit carbon dioxide (CO2) emissions. A major sink for atmospheric CO2, and a key source of biological resources, the World Ocean is widely anticipated to undergo profound physical and – via ocean acidification – chemical changes as direct and indirect results of these emissions. Given strong biophysical coupling, the marine biota is also expected to experience strong changes in response to this anthropogenic forcing. Here we examine the large-scale response of ocean biogeochemistry to climate and acidification impacts during the 21st century for Representative Concentration Pathways (RCPs) 2.6 and 8.5 using an intermediate complexity global ecosystem model, MEDUSA-2.0. The primary impact of future change lies in stratification-led declines in the availability of key nutrients in surface waters, which in turn leads to a global decrease (1990s vs. 2090s) in ocean productivity (?6.3%). This impact has knock-on consequences for the abundance of the low trophic level biogeochemical actors modelled by MEDUSA-2.0 (?5.8%), and these would be expected to similarly impact higher trophic level elements such as fisheries. Related impacts are found in the flux of organic material to seafloor communities (?40.7% at 1000 m), and in the volume of ocean suboxic zones (+12.5%). A sensitivity analysis removing an acidification feedback on calcification finds that change in this process significantly impacts benthic communities, suggesting that a~better understanding of the OA-sensitivity of calcifying organisms, and their role in ballasting sinking organic carbon, may significantly improve forecasting of these ecosystems. For all processes, there is geographical variability in change – for instance, productivity declines ?21% in the Atlantic and increases +59% in the Arctic – and changes are much more pronounced under RCP 8.5 than the RCP 2.6 scenario
Eddies around Madagascar - the retroflection re-considered
The Agulhas Current with its retroflection and attendant eddy-shedding is the cause of some of the greatest mesoscale variability in the ocean. This paper considers the area to the south and east of Madagascar, which provides some of the source waters of the Agulhas Current, and examines the propagating sea surface height signals in altimetry and output from a numerical model, OCCAM. Both show bands of variability along the axis of the East Madagascar Current (EMC) and along a zonal band near 25°S. Sequences of images plus associated temperature data suggest that a number of westward-propagating eddies are present in this zonal band. The paper then focuses on the region to the south of the island, where ocean colour and infra-red imagery are evocative of an East Madagascar Retroflection. The synthesis of data analysed in this paper, however, show that remotely observed features in this area can be explained by anticyclonic eddies moving westward through the region, and this explanation is consistent with numerical model output and the trajectories of drifting buoys
Mozambique Channel Eddies in GCMs: A question of resolution and slippage
Hydrographic observations in the 21st century have shown that the flow within the MozambiqueChannel is best described by a series of large poleward-propagating anticyclonic eddies, rather than, aspreviously thought, a continuous intense western boundary current. The portrayal of this region in various runs of the NEMO 75-level model is found to vary between those two descriptions depending upon the resolution used and the implementation of the model's lateral boundary conditions. In a comparison of 1/4 ? resolution runs, the change of these conditions from free-slip to no-slip leads to the mean southward flow moving further offshore, with greater variability in the zonal and meridional velocities as the flow organises itself into eddies, and a reduction in total transport. If a realization of a model is unable to get these aspects of the physical flow correct, then this will significantly reduce its ability to show a realistic biological signal or long-term response to climate change. Further south, beyond Durban, the application of no-slip conditions similarly causes the mean Agulhas Current to lie further offshore, making it much more able to simulate Natal Pulses.<br/
1ST MEASUREMENT OF GAMMA(D(S)(+)-]MU+NU)/GAMMA(D(S)(+)-]PHI-PI+)
Complete Author List:
ACOSTA D, ATHANAS M, MASEK G, PAAR H, BEAN A, GRONBERG J, KUTSCHKE R, MENARY S, MORRISON RJ, NAKANISHI S, NELSON HN, NELSON TK, RICHMAN JD, RYD A, TAJIMA H, SCHMIDT D, SPERKA D, WITHERELL MS, PROCARIO M, YANG S, BALEST R, CHO K, DAOUDI M, FORD WT, JOHNSON DR, LINGEL K, LOHNER M, RANKIN P, SMITH JG, ALEXANDER JP, BEBEK C, BERKELMAN K, BESSON D, BROWDER TE, CASSEL DG, CHO HA, COFFMAN DM, DRELL PS, EHRLICH R, GALIK RS, GARCIASCIVERES M, GEISER B, GITTELMAN B, GRAY SW, HARTILL DL, HELTSLEY BK, JONES CD, JONES SL, KANDASWAMY J, KATAYAMA N, KIM PC, KREINICK DL, LUDWIG GS, MASUI J, MEVISSEN J, MISTRY NB, NG CR, NORDBERG E, OGG M, PATTERSON JR, PETERSON D, RILEY D, SALMAN S, SAPPER M, WORDEN H, WURTHWEIN F, AVERY P, FREYBERGER A, RODRIGUEZ J, STEPHENS R, YELTON J, CINABRO D, HENDERSON S, KINOSHITA K, LIU T, SAULNIER M, SHEN F, WILSON R, YAMAMOTO H, ONG B, SELEN M, SADOFF AJ, AMMAR R, BALL S, BARINGER P, COPPAGE D, COPTY N, DAVIS R, HANCOCK N, KELLY M, KWAK N, LAM H, KUBOTA Y, LATTERY M, NELSON JK, PATTON S, PERTICONE D, POLING R, SAVINOV V, SCHRENK S, WANG R, ALAM MS, KIM IJ, NEMATI B, ONEILL JJ, SEVERINI H, SUN CR, ZOELLER MM, CRAWFORD G, DAUBENMIER CM, FULTON R, FUJINO D, GAN KK, HONSCHEID K, KAGAN H, KASS R, LEE J, MALCHOW R, MORROW F, SKOVPEN Y, SUNG M, WHITE C, WHITMORE J, WILSON P, BUTLER F, FU X, KALBFLEISCH G, LAMBRECHT M, ROSS WR, SKUBIC P, SNOW J, WANG PL, WOOD M, BORTOLETTO D, BROWN DN, FAST J, MCILWAIN RL, MIAO T, MILLER DH, MODESITT M, SCHAFFNER SF, SHIBATA EI, SHIPSEY IPJ, WANG PN, BATTLE M, ERNST J, KROHA H, ROBERTS S, SPARKS K, THORNDIKE EH, WANG CH, DOMINICK J, SANGHERA S, SHELKOV V, SKWARNICKI T, STROYNOWSKI R, VOLOBOUEV I, ZADOROZHNY P, ARTUSO M, HE D, GOLDBERG M, HORWITZ N, KENNETT R, MONETI GC, MUHEIM F, MUKHIN Y, PLAYFER S, ROZEN Y, STONE S, THULASIDAS M, VASSEUR G, ZHU G, BARTELT J, CSORNA SE, EGYED Z, JAIN V, SHELDON P, AKERIB DS, BARISH B, CHADHA M, CHAN S, COWEN DF, EIGEN G, MILLER JS, OGRADY C, URHEIM J, WEINSTEIN A
The Swift gamma-ray burst redshift distribution: selection biases and optical brightness evolution at high z?
We employ realistic constraints on astrophysical and instrumental selection effects to model the gamma-ray burst (GRB) redshift distribution using Swift triggered redshift samples acquired from optical afterglows and The Optically Unbiased GRB Host survey. Models for the Malmquist bias, redshift desert, and the fraction of afterglows missing because of host galaxy dust extinction are used to show how the `true' GRB redshift distribution is distorted to its presently observed biased distribution. We also investigate another selection effect arising from a correlation between Eiso and Lopt. The analysis, which accounts for the missing fraction of redshifts in the two data subsets, shows that a combination of selection effects (both instrumental and astrophysical) can describe the observed GRB redshift distribution. Furthermore, the observed distribution is compatible with a GRB rate evolution that tracks the global star formation rate, although the rate at high z cannot be constrained with confidence. Taking optical selection effects into account, it may not be necessary to invoke high-energy GRB luminosity evolution with redshift to explain the observed GRB rate at high z
A 2 h periodic variation in the low-mass X-ray binary Ser X-1
Spectroscopy of the low-mass X-ray binary Ser X-1 using the Gran Telescopio Canarias have revealed a ?2 h periodic variability that is present in the three strongest emission lines. We tentatively interpret this variability as due to orbital motion, making it the first indication of the orbital period of Ser X-1. Together with the fact that the emission lines are remarkably narrow, but still resolved, we show that a main-sequence K dwarf together with a canonical 1.4 M? neutron star gives a good description of the system. In this scenario, the most likely place for the emission lines to arise is the accretion disc, instead of a localized region in the binary (such as the irradiated surface or the stream-impact point), and their narrowness is due instead to the low inclination (?10°) of Ser X-1
Serum HE4 as a prognostic marker in endometrial cancer - a population based study
Abstract not availableDonal J. Brennan, Andreas Hackethal, Alex M. Metcalf, Jermaine Coward, Kaltin Ferguson, Martin K. Oehler, Michael A. Quinn, Monika Janda, Yee Leung, Michael Freemantle, ANECS Group, Penelope M. Webb, Amanda B. Spurdle, Andreas Obermai
Exclusive and inclusive semileptonic decays of B mesons to D mesons
complete author list: Fulton R.; Jensen T.; Johnson D.; Kagan H.; Kass R.; Morrow F.; Whitmore J.; Wilson P.; Bortoletto D.; Chen W.; Dominick J.; McIlwain R.; Miller D.; Ng C.; Schaffner S.; Shibata E.; Shipsey I.; Yao W.; Battle M.; Sparks K.; Thorndike E.; Wang C.; Alam M.; Kim I.; Li W.; Romero V.; Sun C.; Wang P.; Zoeller M.; Goldberg M.; Haupt T.; Horwitz N.; Jain V.; Mestayer M.; Moneti G.; Rozen Y.; Rubin P.; Sharma V.; Skwarnicki T.; Thulasidas M.; Zhu G.; Csorna S.; Letson T.; Alexander J.; Artuso M.; Bebek C.; Berkelman K.; Browder T.; Cassel D.; Cheu E.; Coffman D.; Crawford G.; Dewire J.; Drell P.; Ehrlich R.; Galik R.; Garcia-Sciveres M.; Geiser B.; Gittelman B.; Gray S.; Halling A.; Hartill D.; Heltsley B.; Honscheid K.; Kandaswamy J.; Katayama N.; Kreinick D.; Lewis J.; Ludwig G.; Masui J.; Mevissen J.; Mistry N.; Nandi S.; Nordberg E.; O'Grady C.; Peterson D.; Pisharody M.; Riley D.; Sapper M.; Selen M.; Silverman A.; Stone S.; Worden H.; Worris M.; Sadoff A.; Avery P.; Besson D.; Garren L.; Yelton J.; Kinoshita K.; Pipkin F.; Procario M.; Wilson R.; Wolinski J.; Xiao D.; Zhu Y.; Ammar R.; Baringer P.; Coppage D.; Davis R.; Haas P.; Kwak N.; Lam H.; Ro S.; Kubota Y.; Nelson J.; Perticone D.; Poling R.; Fulton R.; Poling R.; Perticone D.; Nelson J.; Fulton R.</p
Iron and titanium amino-phenolate complexes in controlled alkene polymerisation
Transition metals have long been used as both catalysts and mediators in the polymerisation
of many monomers. This thesis explores the use of iron and titanium amino-phenolate
complexes as mediators in the polymerisation of alkene monomers.
Initial work focused on understanding the fundamental mechanisms behind the
organometallic-mediated radical polymerisation (OMRP) of styrene, methyl methacrylate
(MMA) and vinyl acetate using a novel and fully characterised tert-butyl substituted aminebis(phenolate) iron(II) complex. A range of temperatures and conditions were explored to
elucidate the equilibrium between propagation and termination reactions in the
polymerisation. It was found that in the polymerisation of MMA, propagation was favoured
at low conversion with good control and reasonable dispersities. Mechanistic studies suggest
that propagation proceeds through a reversible-termination OMRP mechanism. At higher
conversions, irreversible termination reactions become dominant. The polymerisation
temperature significantly affects the nature of termination, dictating whether termination is
either bimolecular or via catalytic chain transfer (CCT). The polymerisation of styrene shows
well-controlled behaviour with dispersities as low as 1.27, which is the first time this has been
achieved for iron-mediated OMRP. The use of alternative initiation methods, such as
macroinitiators and photoinitiators, is also discussed.
A family of titanium(III) amino-phenolate complexes were used as mediators in the
polymerisation of methacrylates. Well-controlled polymerisations were achieved, with linear
first-order kinetics and dispersities as low as 1.09. The nature of the substituents on the
ligand greatly affects the tacticity of the resultant polymer, with large bulky groups having a
more significant effect in promoting isotactic polymer. Detailed experimental and
computational studies suggest that the polymerisation mechanism is not radical or ionic, but
instead proceeds through a coordinating-type mechanism. This mechanism is suggested to
be bimetallic, involving a titanium(IV)-enolate complex and an MMA-coordinated
titanium(III) species, with polymerisation propagating via a group transfer mechanism, which
is rarely exhibited in transition metals. This also likely represents the first example of the
initiation of a coordination polymerisation with a conventional azo initiator, without the need
for pyrophoric or expensive activators
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