133,385 research outputs found
Space charge and charge trapping characteristics of cross-linked polyethylene subjected to ac electric stresses
No full textThis paper reports on the result of space charge evolution in cross-linked polyethylene (XLPE) planar samples of approximately 220 ?m thick. The space charge measurement technique used in this study is the PEA method. There are two phases to this experiment. In the first phase, the samples were subjected to dc 30 kVdc/mm and ac (sinusoidal) electric stress level of 30 kVpk/mm at frequencies of 1 Hz, 10 Hz and 50 Hz ac. In addition, ac space charge under 30 kVrms/mm and 60 kVpk/mm electric stress at 50 Hz was also investigated. The volts off results showed that the amount of charge trapped in XLPE sample under dc electric stress is significantly bigger than samples under ac stress even when the applied ac stresses are substantially higher. The second phase of the experiment involves studying the dc space charge evolution in samples that were tested under ac stress during the first phase of the experiment. Ac ageing causes positive charge to become more dominant over negative charge. It was also discovered that ac ageing creates deeper traps, particularly for negative charge. This paper also gave a brief overview of the data processing methods used to analyse space charge under ac electric stress
INNOVATIVE PILLAR[6]ARENE-BASED STATIONARY PHASES FOR HIGH-RESOLUTION GAS CHROMATOGRAPHIC ANALYSES
No full textIn this work, the synthesis, fabrication, and characterization of new stationary phases based on pillar[6]arene derivative modified by long alkyl chains (P6A-C10) for high-resolution gas chromatographic (GC) analyses are reported. Pillar[n]arenes are a new class of macrocyclic hosts that can accommodate specific guests due to their highly symmetrical and rigid pillar architectures with π-electron rich cavities. Quantum chemistry calculations have been performed, showing a difference in non-covalent interactions with the P6A-C10 pillar framework, which leads to specific selectivity for aromatic compounds. The GC columns prepared with these innovative stationary phases exhibited a medium polarity, and good reproducibility for run-to-run, day-to-day, and column-to-column analyses [1], demonstrating great potential as new stationary phases in separation science. Furthermore, peculiar advantages are achieved if compared with the commercial HP-5, HP-35, DB-17, and PEG-20M columns, showing unmatched resolving capabilities toward chloroaniline, bromoaniline, iodoaniline, toluidine, and xylene isomers [2].
References:
1. Sun, T., Chen, R., Huang, Q., Ba, M., Cai, Z., Hu, S., Liu, X., Nardiello, D., & Quinto, M., ACS Appl. Mater. Interfaces 14 (2022) 56132−56142.
2. Sun, T., Chen, R., Huang, Q., Ba, M., Cai, Z., Chen, H., Qi, Y., Chen, H., Liu, X., Nardiello, D., & Quinto, M., Anal. Chim. Acta 1251 (2023) 340979
Effect of polyethylene interface on space charge formation
No full textThis paper reports the results of an investigation into the space charge formation and decay at different material interfaces. In particular, the influence of the interface between electrode and polymer or polymer and polymer on the space charge dynamics has been studied. Planar samples were subjected to high dc electric stresses for extended periods of time and space charge measurements taken using the pulsed electroacoustic (PEA) technique. It has been found that the types of interface between electrode and polymer play a significant role in determining the charge distribution in the insulation and that the interface between polymer and polymer acts as a potential barrier to electrons whilst allowing positive charge carriers through easily
Optical detection of deoxyribonucleic acid hybridization with InGaN/GaN multiple quantum wells
No full text
Regularized transport between singular covariance matrices
Full text linkWe consider the problem of steering a linear stochastic system between two end-point degenerate Gaussian distributions in finite time. This accounts for those situations in which some but not all of the state entries are uncertain at the initial, t = 0, and final time, t = T. This problem entails non-trivial technical challenges as the singularity of terminal state-covariance causes the control to grow unbounded at the final time T. Consequently, the entropic interpolation (Schroedinger Bridge) is provided by a diffusion process which is not finite-energy, thereby placing this case outside of most of the current theory. In this paper, we show that a feasible interpolation can be derived as a limiting case of earlier results for non-degenerate cases, and that it can be expressed in closed form. Moreover, we show that such interpolation belongs to the same reciprocal class of the uncontrolled evolution. By doing so we also highlight a time-symmetry of the problem, contrasting dual formulations in the forward and reverse time-directions, where in each the control grows unbounded as time approaches the end-point (in the forward and reverse time-direction, respectively)
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