1,492 research outputs found
Two‐Dimensional Supramolecular Chemistry on Surfaces
No full textSupramolecular chemistry represents one of the central themes of modern chemical sciences. The use of supramolecular interactions to create complex supermolecules and self-assembled arrays on surfaces represents a new avenue of research with promise for the development of molecular-level devices
Characterisation and Interpretation of On‐Surface Chemical Reactions Studied by Ultra‐High‐Resolution Scanning Probe Microscopy
No full textThe investigation of supramolecular self-assembly at surfaces requires detailed characterisation at the molecular or even sub-molecular level. The primary technique that has been employed to ensure a detailed understanding of self-assembled structures is based on high-resolution scanning probe microscopy (SPM). Such techniques, notably scanning-tunnelling microscopy (STM) and atomic force microscopy (AFM) have been widely used and such techniques allow the resolution of the geometric structure of organic molecules with intramolecular resolution. The development of noncontact atomic force microscopy (ncAFM) over recent years has allowed sub-molecular imaging of the chemical, electronic, and electrostatic properties of single molecules. This chapter focuses on the use of this technique to track complex on-surface chemical reactions, investigate novel reaction products, and even synthesise new molecular structures one bond at a time
Surface Self‐Assembly of Hydrogen‐Bonded Frameworks
No full textThe use of intermolecular hydrogen bonds to create two-dimensional arrays on surfaces is discussed. In particular, the supramolecular synthon strategy, is described which in principle allows the rational design and synthesis of hydrogen-bonded arrays and frameworks. The success or otherwise of using this approach is discussed, and remarkable examples of porous frameworks capable of trapping guest molecules, as well as complex and intricate design strategies that lead to tiling assemblies, are explored. Ultimately, the successful implementation of the supramolecular synthon strategy using hydrogen bonds is demonstrated, coupled with an appreciation of the complexity of energetic preferences during the self-assembly process
CCDC 1504708: Experimental Crystal Structure Determination
No full textRelated Article: Jamie A. Gould, Harprit Singh Athwal, Alexander J. Blake, William Lewis, Peter Hubberstey, Neil R. Champness and Martin Schröder|2017|Philos.Trans.R.Soc.London,Ser.A|357|20160334|doi:10.1098/rsta.2016.033
Supramolecular Chemistry on Surfaces:2D Networks and 2D Structures
No full textSupramolecular Chemistry on Surfaces 2D Networks and 2D Structures Explore the cutting-edge in 2D chemistry on surfaces and its applications In Supramolecular Chemistry on Surfaces: 2D Networks and 2D Structures, expert chemist Neil R. Champness delivers a comprehensive overview of the rapidly developing field of two-dimensional supramolecular chemistry on surfaces. The book offers explorations of the state-of-the-art in the discipline and demonstrates the potential of the latest advances and the challenges faced by researchers in different areas. The editor includes contributions from leading researchers that address new spectroscopic methods which allow for investigations at a sub-molecular level, opening up new areas of understanding in the field. Included resources also discuss important supramolecular strategies, like hydrogen-bonding, van der Waals interactions, metal-ligand coordination, multicomponent assembly, and more. The book also provides:- A thorough introduction to two-dimensional supramolecular chemistry on surfaces - Comprehensive explorations of the characterization and interpretation of on-surface chemical reactions studied by ultra-high resolution scanning probe microscopy - Practical discussions of complexity in two-dimensional multicomponent assembly, including explorations of coordination bonds and quasicrystalline structures - In-depth examinations of covalently bonded organic structures via on-surface synthesis Perfect for polymer chemists, spectroscopists, and materials scientists, Supramolecular Chemistry on Surfaces: 2D Networks and 2D Structures will also earn a place in the libraries of physical and surface chemists, as well as surface physicists.</p
CCDC 1504706: Experimental Crystal Structure Determination
No full textRelated Article: Jamie A. Gould, Harprit Singh Athwal, Alexander J. Blake, William Lewis, Peter Hubberstey, Neil R. Champness and Martin Schröder|2017|Philos.Trans.R.Soc.London,Ser.A|357|20160334|doi:10.1098/rsta.2016.033
CCDC 1504707: Experimental Crystal Structure Determination
No full textRelated Article: Jamie A. Gould, Harprit Singh Athwal, Alexander J. Blake, William Lewis, Peter Hubberstey, Neil R. Champness and Martin Schröder|2017|Philos.Trans.R.Soc.London,Ser.A|357|20160334|doi:10.1098/rsta.2016.033
Supramolecular Chemistry on Surfaces:2D Networks and 2D Structures
No full textSupramolecular Chemistry on Surfaces 2D Networks and 2D Structures Explore the cutting-edge in 2D chemistry on surfaces and its applications In Supramolecular Chemistry on Surfaces: 2D Networks and 2D Structures, expert chemist Neil R. Champness delivers a comprehensive overview of the rapidly developing field of two-dimensional supramolecular chemistry on surfaces. The book offers explorations of the state-of-the-art in the discipline and demonstrates the potential of the latest advances and the challenges faced by researchers in different areas. The editor includes contributions from leading researchers that address new spectroscopic methods which allow for investigations at a sub-molecular level, opening up new areas of understanding in the field. Included resources also discuss important supramolecular strategies, like hydrogen-bonding, van der Waals interactions, metal-ligand coordination, multicomponent assembly, and more. The book also provides:- A thorough introduction to two-dimensional supramolecular chemistry on surfaces - Comprehensive explorations of the characterization and interpretation of on-surface chemical reactions studied by ultra-high resolution scanning probe microscopy - Practical discussions of complexity in two-dimensional multicomponent assembly, including explorations of coordination bonds and quasicrystalline structures - In-depth examinations of covalently bonded organic structures via on-surface synthesis Perfect for polymer chemists, spectroscopists, and materials scientists, Supramolecular Chemistry on Surfaces: 2D Networks and 2D Structures will also earn a place in the libraries of physical and surface chemists, as well as surface physicists.</p
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