1,720,984 research outputs found
Generalized fluctuation–dissipation relations holding in non-equilibrium dynamics
Full text linkWe derive generalized fluctuation–dissipation relations (FDR) holding for a general stochastic dynamics that includes as subcases both equilibrium models for passive colloids and non-equilibrium models used to describe active particles. The relations reported here differ from previous formulations of the FDR because of their simplicity: they require only the microscopic knowledge of the dynamics instead of the whole expression of the steady-state probability distribution function that, except for linear interactions, is unknown for systems displaying non-vanishing currents. From the response function, we can extrapolate generalized versions of the mesoscopic virial equation and the equipartition theorem, which still holds far from equilibrium. Our results are tested in the case of equilibrium colloids described by underdamped or overdamped Langevin equations and for models describing the non-equilibrium behavior of active particles. Both the active Brownian particle and the active Ornstein–Uhlenbeck particle models are compared in the case of a single particle confined in an external potential
Flocking without alignment interactions in attractive active Brownian particles
Full text linkWithin a simple model of attractive active Brownian particles, we predict flocking behavior and challenge the widespread idea that alignment interactions are necessary to observe this collective phenomenon. Here, we show that even nonaligning attractive interactions can lead to a flocking state. Monitoring the velocity polarization as the order parameter, we reveal the onset of a first-order transition from a disordered phase, characterized by several small clusters, to a flocking phase, where a single flocking cluster is emerging. The scenario is confirmed by studying the spatial connected correlation function of particle velocities, which reveals scale-free behavior in flocking states and exponential-like decay for nonflocking configurations. Our predictions can be tested in microscopic and macroscopic experiments showing flocking, such as animals, migrating cells, and active colloids
How a local active force modifies the structural properties of polymers
Full text linkWe study the dynamics of a polymer, described as a variant of a Rouse chain, driven by an active terminal monomer (head). The local active force induces a transition from a globule-like to an elongated
state, as revealed by the study of the end-to-end distance, the variance of which is analytically predicted under suitable approximations. The change in the relaxation times of the Rouse-modes produced by the local self-propulsion is consistent with the transition from globule to elongated conformations. Moreover, also the bond–bond spatial correlation for the chain head are affected by the self-propulsion and a gradient of over-stretched bonds along the chain is observed. We compare our numerical results both with the phenomenological stiff-polymer theory and several analytical predictions in the Rousechain approximation
Self-reverting vortices in chiral active matter
Full text linkThere is currently a strong interest in the collective behavior of chiral active particles that can propel and rotate themselves. In the presence of alignment interactions for many chiral particles, chiral self-propulsion can induce vortex patterns in the velocity fields. However, these emerging patterns are non-permanent, and do not induce global vorticity. Here we combine theoretical arguments and computer simulations to predict a so-far unknown class of collective behavior. We show that, for chiral active particles, vortices with significant dynamical coherence emerge spontaneously. They originate from the interplay between attraction interactions and chirality in the absence of alignment interactions. Depending on parameters, the vortices can either feature a constant vorticity or a vorticity that oscillates periodically in time, resulting in self-reverting vortices. Our results may guide future experiments to realize customized collective phenomena such as spontaneously rotating gears and patterns with a self-reverting order.In many chiral particle systems, vortex patterns emerge in the velocity fields due to the alignment interactions, but these patterns are non-permanent and decohere quickly. The authors predict the spontaneous emergence of vortices with high dynamical coherence, and identify the transition between the regimes of constant and oscillating vorticity
Irreversibility and typicality: A simple analytical result for the Ehrenfest model
No full textWith the aid of simple analytical computations for the Ehrenfest model, we clarify some basic features of macroscopic irreversibility. The stochastic character of the model allows us to give a non-ambiguous interpretation of the general idea that irreversibility is a typical property: for the vast majority of the realizations of the stochastic process, a single trajectory of a macroscopic observable behaves irreversibly, remaining “very close” to the deterministic evolution of its ensemble average, which can be computed using probability theory. The validity of the above scenario is checked through simple numerical simulations and a rigorous proof of the typicality is provided in the thermodynamic limit
Handy fluctuation-dissipation relation to approach generic noisy systems and chaotic dynamics
No full textWe introduce a general formulation of the fluctuation-dissipation relations (FDRs) holding also in far-from-equilibrium stochastic dynamics. A great advantage of this version of the FDR is that it does not require explicit knowledge of the stationary probability density function. Our formula applies to Markov stochastic systems with generic noise distributions: When the noise is additive and Gaussian, the relation reduces to those known in the literature; for multiplicative and non-Gaussian distributions (e.g., Cauchy noise) it provides exact results in agreement with numerical simulations. Our formula allows us to reproduce, in a suitable small-noise limit, the response functions of deterministic, strongly nonlinear dynamical models, even in the presence of chaotic behavior: This could have important practical applications in several contexts, including geophysics and climate. As a case of study, we consider the Lorenz '63 model, which is paradigmatic for the chaotic properties of deterministic dynamical systems
Ultrafast entropy production in pump-probe experiments
Full text linkThe ultrafast control of materials has opened the possibility to investigate non-equilibrium states of matter with striking properties, such as transient superconductivity and ferroelectricity, ultrafast magnetization and demagnetization, as well as Floquet engineering. The characterization of the ultrafast thermodynamic properties within the material is key for their control and design. Here, we develop the ultrafast stochastic thermodynamics for laser-excited phonons. We calculate the entropy production and heat absorbed from experimental data for single phonon modes of driven materials from time-resolved X-ray scattering experiments where the crystal is excited by a laser pulse. The spectral entropy production is calculated for SrTiO3 and KTaO3 for different temperatures and reveals a striking relation with the power spectrum of the displacement-displacement correlation function by inducing a broad peak beside the eigenmode-resonance.Ultrafast spectroscopy enables characterization and control of non-equilibrium states. Here the authors introduce a stochastic thermodynamics approach to calculate entropy production in a material under ultrafast excitation, using ionic displacement data from time-resolved X-ray scattering experiments
Excess and loss of entropy production for different levels of coarse graining
Full text linkWe investigate the effect of coarse graining on the thermodynamic properties of a system, focusing on entropy production. As a case of study, we consider a one-dimensional colloidal particle in contact with a thermal bath, moving in a sinusoidal potential and driven out of equilibrium by a small constant force. Different levels of coarse graining are evaluated: At first, we compare the results in the underdamped dynamics with those in the overdamped one (first coarse graining). For large values of the friction coefficient, the two dynamics have the same thermodynamics properties, while, for smaller friction values, the overdamped approximation produces an excess of entropy production with respect to that of the underdamped dynamics. Moreover, for further smaller values of the drag coefficient, the excess of entropy production turns into a loss. These regimes are explained by evaluating the jump statistics, observing that the inertia is able to induce multiple jumps and affect the average jump rate. The periodic shape of the potential allows us to approximate the continuous dynamics via a Markov chain after the introduction of a suitable time and space discretization (second level of coarse graining). This discretization procedure is implemented starting both from the underdamped and the overdamped evolution and is analyzed for different values of the friction coefficient
- …
