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    Petrogenesis of mafic lavas from the northernmost sector of the Iblean district (Sicily)

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    A wide spectrum of mafic volcanic rocks, ranging from Qz-tholeiites to strongly undersaturated alkaline lavas (ankaratrites), were erupted during Upper Miocene and Plio-Pleistocene in the Iblean area. The rather primitive nature of these products indicates that the differentiation processes occurred from the source region to the surface affected these magmas only in subordinate way.For this reason, on the basis of the presented chemical and mineralogical data, the petrogenetic study of the Iblean volcanic suite is mainly aimed at constraining and evaluating the partial melting processes and the nature of the mantle sources. The modelling of the available chemical data (both major and trace elements) indicates that these near-primary melts cannot have been produced by different degrees of melting from the same source; this would suggest that their differences reflect, at least in part, significant variations in source composition.The calculations suggest that suitable mantle sources are represented by variously "enriched" spinel-lherzolites, containing accessory phases such as amphibole for tholeiitic and transitional basalts (A-Th, B-Th and TB), amphibole + phlogopite for alkaline lavas (AB, Bn) and amphibole + phlogopite +/- apatite +/- carbonate for highly alkaline rocks (A-Ank, B-Ank).In this light, the wide range of mafic lavas collected in the Iblean area appear to have been produced by different degrees of partial melting, ranging from 2-3% for the highly alkaline rocks to 22 % for the Qz-tholeiites, of a lithospheric mantle characterized by small-scale heterogeneity.This process has been favoured by relatively high thermal conditions in the mantle beneath the studied area and induced by the Miocene and Plio-Pleistocene transcurrent-extensional tectonic regime.The chemical compositions of the various lavas depend on the relative proportions of the differently enriched mantle domains involved. Small degrees of partial melting sampled preferentially low-solidus enriched domains, producing the alkaline magmas. At higher partial melting degrees, larger domains of less enriched mantle portions contributed to the magmatogenetic processes, thus generating the subalkaline magmas

    Environmental impact of the acid fumarole plume of a passively degassing volcano (Vulcano Island, Italy)

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    Abstract This paper investigates the role played by the fumarolic plume of a passive degassing volcano in the genesis of rock coatings (RC) and in the introduction and re-distribution of metals and trace elements in the surficial environment. At La Fossa active volcano (Vulcano Island) and in the surrounding environment RC develop owing to exposure of the ground surface to the volcanic acid plume produced by the passive degassing of La Fossa. Significant positive anomalies of a wide variety of metals and trace elements (including Bi, Ag, Se, Te, Sb, Pb, As, Cu, Tl and Cd) were observed either in distal and proximal RC. Most of these anomalies are interpreted to be the result of the transport and subsequent deposition of trace elements, likely to form volatile compounds, in the fumarolic plume. Two main processes seem to control the geochemistry of RC: one is represented by the leaching and subsequent deposition of elements from the proximal toward the distal RC; the other is the direct input of trace elements carried by the emitted volcanic aerosol. The fact that most of the trace elements (particularly Pb, As, Tl, Bi, Te, Se, Cd) enriched in the RC of Vulcano are highly toxic and potentially dangerous to health in high concentration, indicates that the atmospheric metal injection by the quiescently degassing La Fossa volcano together with the subsequent deposition and remobilization by means of surficial waters may represent an environmental hazard that should be taken into account in evaluating the potential impact of volcanic air pollution on human health
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