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New frontiers in hybrid materials: noble metal nanoparticles – supramolecular gel systems
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Highlights on contemporary recognition and sensing of fluoride anion in solution and in the solid state
No full textSelective adsorption of chlorinated volatile organic compound vapours by microcrystalline 1D coordination polymers
No full textMicrocrystalline 1D coordination polymers 1-3Pwd are able to adsorb vapours of chlorinated volatile organic compounds (Cl-VOCs), displaying interesting selectivity patterns, as demonstrated by 1H-NMR and X-ray diffraction analyses. Due to their dynamic breathing-like behavior, chemical and thermal stabilities and adsorption selectivity, these isostructural coordination polymers are promising to be used as filters for toxic Cl-VOCs
Cu(ii)-specific metallogel formation by an amido-anthraquinone-pyridyloxalamide ligand in DMSO–water
No full textDynamic single crystal to polycrystal transformation of a 1D-coordination polymer and its second harmonic generation
No full textUpon guest CHCl3 release, the one-dimensional (1D) coordination polymer 1·CHCl3 gives rise to a non-porous structure, 1, following a unit cell volume reduction of ca. 22%. Due to the considerable structural transformation, the single crystal does not maintain its integrity, and therefore the structure determination has been carried out by combining single crystal X-ray diffraction and ab initio X-ray powder diffraction analyses. The result shows a symmetry breaking transformation leading to an acentric crystalline material (1), which shows nonlinear optical properties such as second harmonic generatio
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