3,961 research outputs found

    Natural convection of a two-dimensional Boussinesq fluid does not maximize entropy production

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    Rayleigh-Bénard convection is a canonical example of spontaneous pattern formation in a nonequilibrium system. It has been the subject of considerable theoretical and experimental study, primarily for systems with constant (temperature or heat flux) boundary conditions. In this investigation, we have explored the behavior of a convecting fluid system with negative feedback boundary conditions. At the upper and lower system boundaries, the inward heat flux is defined such that it is a decreasing function of the boundary temperature. Thus the system's heat transport is not constrained in the same manner that it is in the constant temperature or constant flux cases. It has been suggested that the entropy production rate (which has a characteristic peak at intermediate heat flux values) might apply as a selection rule for such a system. In this work, we demonstrate with Lattice Boltzmann simulations that entropy production maximization does not dictate the steady state of this system, despite its success in other, somewhat similar scenarios. Instead, we will show that the same scaling law of dimensionless variables found for constant boundary conditions also applies to this system

    Avenues for emergent ecologies

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    In this work, we present some fascinating behaviour emerging from a simple synthetic chemistry model. The results of Ono and Ikegami (2001) demonstrated the spontaneous formation of primitive, self-reproducing cells from a random homogeneous mixture of chemical components. Their model made use of a simple, artificial reaction network. Discrete particles were placed on a triangular lattice and the dynamics consisted of the following particle transitions: translation over one lattice spacing and chemical transformation. The primary particle types were membrane-forming particles, catalysts and water. The membrane particles formed structures akin to lipid bilayers. Their synthesis was stimulated by the catalyst particles, which were also capable of template self-replication using precursors. The system readily exhibits protocell formation from a random initial condition. These protocells form, grow, divide and eventually decay in a continuous cycle. Such emergent dynamics were an illuminating result given that the simulation itself only defines local interactions between particles and a set of physical transition rules. The protocell structures are not explicitly represented or built into the model. Hence it demonstrated a basic physical logic wherein the concepts of self-maintenance and self-reproduction could arise spontaneously from a set of simpler, lower level rules. In essence, it was an in silico realisation of the principle of autopoiesis.We decided to extend this work by augmenting the particle species repertoire. An additional catalyst was added, which did not stimulate the synthesis of membrane particles, but rather stimulated their decay. It was expected that this would reduce the rate of protocell formation. However a surprising dynamic was uncovered with this new system. As one might expect the protocells did not arise in abundance as in the original model. Instead they formed in small, isolated colonies since this was the only means by which they could avoid the destructive effects of the new catalyst. However because this toxic particle was also autocatalytic (like the other, constructive catalyst), its concentration rose sharply in regions confined by membrane particles since the membranes slowed their outward diffusion. Thus membranes actually created a niche for the toxic catalyst. This in turn produced a predator-prey dynamic with clouds of the toxic particle growing near protocells and protocells being forced to grow in the opposite direction to avoid the destructive effects of the new particle. These results reveal that high level, ecological phenomena can manifest themselves even in simple physico-chemical systems. They demonstrate that ideas of natural selection and fitness are intimately bound with the basic principle of free energy minimisation. We have also now enhanced the model further by adding a second reaction network. It is similar, but independent to the first and allows for two "species" of protocell. It is also possible for hybrids to form, comprised of mixtures of the membrane particles from the two reaction networks. Results from this new version are currently being gathered and analyse

    Tennessee roads / Jesse Stuart. In Mountain herald / Lincoln Memorial University.

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    This picturesque poem was written by then-sophomore (and future celebrated author) Jesse Stuart about the roads of Tennessee

    No. 617 Stuart Ruckman

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    Transcript (12, 40 pages) of two interviews by Matt Driscoll with Stuart Ruckman on April 9, 2010, and July 7, 2011Ruckman (b. 1966) was born in Salt Lake City, Utah. Stuart shares how his family, particularly his father, played a significant role in introducing him to the outdoors. Some of his initial explorations included a hike to the top of Mount Olympus when he was five years old, backpacking trips in the Wasatch and Uinta Mountains, and a successful summit attempt on the Grand Teton when he was twelve. Stuart discovered technical rock climbing due to the influence of his older brother Bret, five years Stuart\u27s senior. Bret learned under Dennis Turville, a well-respected Salt Lake climbing instructor. Stuart shares his observations on the Salt Lake climbing community of the late 1970s and 1980s, noting the intimacy of the community, while also pointing out the significant influence of a handful of climbers, including Merrill Bitter, Les Ellison, and Brian Smoot. He briefly describes the proliferation of new-route development in the Wasatch during his first decade in climbing. In collaboration with his brother Bret, Stuart published comprehensive guidebooks on climbing in the Wasatch Mountains. Stuart\u27s contributions as a first-ascensionist and co-author of Rock Climbing the Wasatch Range attest to his lasting impact on Utah climbing. Interview is part of the Outdoor Recreation History Project. Interviewer: Matt Driscol

    Coming Phase to Phase with Surfactants

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    We introduce a fast cellular automata model for the simulation of surfactant dynamics based on a previous model by Ono and Ikegami (2001). Here, individual lipid-like particles undergo stochastic movement and rotation on a two-dimensional lattice in response to potential energy gradients. The particles are endowed with an internal structure that reflects their amphiphilic character. Their head groups are weakly repelled by water whereas their hydrophobic tails cannot be readily hydrated. This leads to the formation of a variety of structures when the particles are placed in solution. The model in its current form compels a myriad of potential self-organisation experiments. Heterogeneous boundary conditions, chemical interactions and an arbitrary diversity of particles can easily be modelled. Our main objective was to establish a computational platform for investigating how mechanisms of lipid homeostasis might evolve among populations of protocells

    Emergence of competition between different dissipative structures for the same free energy source

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    In this paper, we explore the emergence and direct interaction of two different types of dissipative structure in a single system: self-replicating chemical spot patterns and buoyancy-induced convection rolls. A new Lattice Boltzmann Model is developed, capable of simulating fluid flow, heat transport, and thermal chemical reactions, all within a simple, efficient framework. We report on a first set of simulations using this new model, wherein the Gray-Scott reaction diffusion system is embedded within a non isothermal fluid undergoing natural convection due to temperature gradients. The non-linear reaction which characterises the Gray-Scott system is given a temperature-dependent rate constant of the form of the Arrhenius equation. The enthalpy change (exothermic heat release or endothermic heat absorption) of the reaction can also be adjusted, allowing a direct coupling between the dynamics of the reaction and the thermal fluid flow.The simulations show positive feedback effects when the reaction is exothermic, but an intriguing, competitive and unstable behaviour occurs when the reaction is sufficiently endothermic. In fact when convection plumes emerge and grow, the reaction diffusion spots immediately surround them, since they require a source of heat for the reaction to proceed. Then however, the proliferation of spot patterns dampens the local temperature, eventually eliminating the initial convection plume and reducing the ability of the spots to persist. This behaviour appears almost ecological, similar as it is, to competitive interactions between organisms competing for the same nutrient source

    George MacLeod’s open-air preaching: performance and counter-performance

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    Stuart Blythe uses the methodology of performance to analyse George MacLeod’s open-air preaching. He points out that MacLeod’s preaching was derived from a theology of the incarnation, and an understanding of the paradoxes and dichotomies of common human life. This preaching, Blythe suggests, was also a counter-performance in the context of outlooks and ideologies inimical to the gospel. The paper raises interesting issues related to preaching as performance, and the further question as to whether or not the life and work of the Church as a whole might now be better understood as a counter-performance.Publisher PD

    Why is life? An assessment of the thermodynamic properties of dissipative, pattern-forming systems

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    This document charts a series of investigations into some basic questions concerning the relationship between life and the physical theories of thermodynamics. While equilibrium thermodynamics represents a foundational component of modern physics, methods for non equilibrium systems have yet to reach the same level of maturity. The first part of this thesis aims to establish the validity of a burgeoning theory of non-equilibrium thermodynamics known as the Maximum Entropy Production Principle (MEPP), in the context of heat transfer by convective fluid motion between heated boundaries. Applying the MEPP to systems with both fixed and negative feedback boundary conditions revealed that in fact, the steady state of convective fluids cannot be accurately predicted from an assumption of maximum entropy production alone. Rather the subtleties of the boundary conditions and the physical properties of the fluid must be properly accounted for. It is thus proposed that the MEPP should not, as has sometimes been suggested, be treated as a universally applicable law of nature. The second part of this thesis investigates the pattern-forming and transport properties of reactive fluid systems. It is found that under thermal driving forces, closed systems utilise the physical processes of reaction and advection to augment their heat transport abilities. Furthermore, the addition of thermal kinetics and fluid flow to the Gray-Scott reaction diffusion system, reveals a new range of phenomena including positive feedback, self-inhibition, competition and symbiosis. Such behaviour can readily be viewed from an ecological, rather than purely physico-chemical, perspective

    Redemption in the work of Francis Stuart

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    The idea of redemption is central to an understanding of the work of Francis Stuart. Through an examination of its development and expression, it is possible to demonstrate the integrity of his work and its distinctive qualities. Such a demonstration is necessary because Stuart's writing has been subjected to comparatively little scholarly inquiry, although reviews of his work, especially that produced since 1949, suggest that it is impressive and important. First, a general background to Stuart's work, a discussion of the special problems associated with reading it, and a summary of his corpus is provided. This indicates that the idea of redemption is important to his earliest writing. The state of redemption is shown to be a necessary apotheosis for Stuart's outcast heroes; it involves spiritual suffering through which may be found a sense of reintegration and a higher reality. This is expressed through interrelated themes such as those of gambler, artist and ordinary man; mystic and criminal; sacred and profane love; and spirituality and the mundane. The nature of the redemptive experience is further elaborated by distinctive, complex motifs, especially the hare, the ark and the woman-Christ. Their recurrence provides an important element in the unity of Stuart's work. Because Stuart's idea of the outcast raises important biographical questions, an examination of the relationship between Stuart's life and his work is made. Finally, the way in which the idea of redemption exists in the language structures of Stuart's novels is examined, with especial reference to his most recent work, The High Consistory. The thesis shows that the development of the these of redemption demonstrates the integrity of Stuart's work

    John Stuart Mill’s projected science of society: 1827-1848

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    The purpose of the thesis is to examine John Stuart Mill’s political thought from about 1827 to 1848 as an exercise in intellectual history. It focuses, first, on Mill’s view, formulated by the late 1830s, that contemporary society was ‘civilized’, and second, on his project of a science of society, which he aspired to develop in the late 1830s and early 1840s. By the late 1830s, Mill came to the view that his contemporary society was a ‘commercial society or civilization’, dominated by the middle, commercial class. The first part of my thesis, constituted by Chapters 2-4, discusses the way in which Mill formed his notion of civilization, and what he meant by the term ‘civilization’. Mill paid attention to the implications of the rise of the middle class, and regarded such phenomena of contemporary society as the corruption of the commercial spirit and excessive social conformity as an inevitable consequence of the rise of the middle class. The second part of the thesis, constituted by Chapters 5-9, examines Mill’s projected science of society. In the late 1830s and early 1840s, Mill attempted to develop a new science of society whose subject-matter was the nature and prospects of commercial, civilized society. This aspiration culminated in A System of Logic, published in 1843. In examining Mill’s projected science, I pay particular attention to the fact that he conceived new sciences of history and of the formation of character, both of which were indispensable in his project, although he failed to give a complete account of these sciences. My thesis shows that the implications of his interest both in history and in the formation of character are more significant than Mill scholars have assumed
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