1,487 research outputs found
DSSC anchoring groups: a surface dependent decision
No full textElectrodes in dye sensitised solar cells are typically nanocrystalline anatase TiO2 with a majority (1 0 1) surface exposed. Generally the sensitising dye employs a carboxylic anchoring moiety through which it adheres to the TiO₂ surface. Recent interest in exploiting the properties of differing TiO₂ electrode morphologies, such as rutile nanorods exposing the (1 1 0) surface and anatase electrodes with high percentages of the (0 0 1) surface exposed, begs the question of whether this anchoring strategy is best, irrespective of the majority surface exposed. Here we address this question by presenting density functional theory calculations contrasting the binding properties of two promising anchoring groups, phosphonic acid and boronic acid, to that of carboxylic acid. Anchor-electrode interactions are studied for the prototypical anatase (1 0 1) surface, along with the anatase (0 0 1) and rutile (1 1 0) surfaces. Finally the effect of using these alternative anchoring groups to bind a typical coumarin dye (NKX-2311) to these TiO₂ substrates is examined. Significant differences in the binding properties are found depending on both the anchor and surface, illustrating that the choice of anchor is necessarily dependent upon the surface exposed in the electrode. In particular the boronic acid is found to show the potential to be an excellent anchor choice for electrodes exposing the anatase (0 0 1) surface
Polymer multimode waveguide optical and electronic PCB manufacturing
No full textThe paper describes the research in the £1.3 million IeMRC Integrated Optical and Electronic Interconnect PCB Manufacturing (OPCB) Flagship Project in which 8 companies and 3 universities carry out collaborative research and which was formed and is technically led by the author. The consortium’s research is aimed at investigating a range of fabrication techniques, some established and some novel, for fabricating polymer multimode waveguides from several polymers, some formulations of which are being developed within the project. The challenge is to develop low cost waveguide manufacturing techniques compatible with commercial PCB manufacturing and to reduce their alignment cost. The project aims to take the first steps in making this hybrid optical waveguide and electrical copper track printed circuit board disruptive technology widely available by establishing and incorporating waveguide design rules into commercial PCB layout software and transferring the technology for fabricating such boards to a commercial PCB manufacturer. To focus the research the project is designing an optical waveguide backplane to tight realistic constraints, using commercial layout software with the new optical design rules, for a demonstrator into which 4 daughter cards are plugged, each carrying an aggregate of 80 Gb/s data so that each waveguide carries 10 Gb/s
The Chance and Probability Concepts Project
No full textThis article, created by D.R. Green, describes an investigation of what concepts and intuitions concerning random processes are present in the minds of children of varying abilities across the 11-16 age range. The ability to list permutations, combinations and arrangements is also being investigated. The author states, "Over the past two decades the topic of 'Probabilityâ has been brought into the mathematics curriculum but it may be that this is more an empty gesture rather than a sound strategy." This article can help to alleviate many of the struggles in teaching probability concepts. The article is pitched at a more elementary audience, but is still a perfect resource for almost anyone teaching in the field
Achieving 10 ps coincidence time resolution in TOF-PET is an impossible dream
No full textGreen Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.RST/Radiation, Science and TechnologyRST/Medical Physics & Technolog
Bepalen van het massatraagheidsmoment met behulp van een bifilar pendulum: Determining the moments of inertia using a bifilar pendulum
No full textThe aim of this thesis is to investigate the use of a bifilar pendulum for determining the moments of inertia of the TU Delft solar boat and to quantitatively predict the estimates. In the first part, several methods are discussed which can be applied in deriving the equations of motion of the pendulum. A new method, Kane's method, will be introduced. In the second part, this method will be used to derive the actual equations of motion. These equations are linearized around of the the pendulum's stationary positions to obtain expressions which link the moment of inertia about an axis to the period of oscillation of the pendulum about that axis. These equations are subsequently applied to the solar boat to derive estimates for the moments of inertia about the principle axis of the boat. The results of this thesis considers three different configurations of the bifilar pendulum with the solar boat suspended. One of these configurations results in the most accurate estimates for the moments of inertia, however, these have not been quantitatively predicted. The author suggests a modification in the definition of the bifilar pendulum such that this might be possible.Electrical Engineering, Mathematics and Computer ScienceNumerical analysi
An introduction to management science: quantitative approaches to decision making
No full textRetaining the accessible application-driven approach for which An Introduction to Management Science is highly regarded, adapting author Mik Wisniewski has carefully reworked the existing US textbook to benefit students across the UK, Europe, Middle East and Africa. Packed with diverse realistic examples from Scotland to Saudi Arabia, the landmark text from the ASW team is now available in a truly internationalised version for students studying Management Science and Operations Research at postgraduate and undergraduate level
Immunotherapy
No full textA chapter covering metastasis immunotherapy in multi-author volume devoted to all aspects of cancer metastasis
An efficient and robust technique for achieving self consistency in electronic structure calculations
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