3,340 research outputs found

    Synthesis optimization and charge carrier transfer mechanism in LiLuSiO<sub>4</sub>:Ce, Tm storage phosphor

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    LiLuSiO4:Ce and LiLuSiO4:Ce, Tm show very efficient charge carrier storage properties upon beta irradiation after samples have received treatment in vacuum. They outperform the commercial storage phosphor BaFBr(I):Eu2+ in many aspects. The influence of the synthesis conditions, Ce and Tm concentration, nonstoichiometry and codoping with Ca, Hf, Al and Ge are reported. Based on the results of the synthesis optimization, thermoluminescence (TL) emission and TL excitation spectra a mechanism of charge carrier transfer, storage, and recombination during irradiation and thermal or optical readout is proposed.Accepted Author ManuscriptRST/Fundamental Aspects of Materials and EnergyRST/Luminescence Material

    Comparative electrochemical performance of electrodeposited polypyrrole in protic and aprotic ionic liquids

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    Polypyrrole (Ppy) thin films were obtained by pyrrole (py) electropolymerization in ionic liquid (IL) media. The charge compensation dynamics as well as the electrochromic behavior of the obtained films were studied in two ILs with similar structures, being one containing –CH3 (aprotic IL) and the other containing –H (protic IL) attached to the ethylimidazolium cation. The results obtained with quartz crystal microbalance with dissipation combined with cyclic voltammetry have shown that in spite of the presence of protons in the PIL, which could favor both electropolymerization and electrochemistry of Ppy in this media, these processes are more effective in the aprotic IL, leading us to conclude that other factors must be take into account when choosing the most appropriated IL as electrolyte. Also, electrochemical reactions in both ILs were successfully associated to the transformation of chromogenic species by evaluating the electrochromic activity of the polymeric films.Fil: Fernández, Ricardo Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Machado Benedetti, Tǎnia. Universidade de Sao Paulo; BrasilFil: Torresi, Roberto M.. Universidade de Sao Paulo; Brasi

    A Comparative Study of the Mott-Schottky Behavior of Oxide Films on Stainless Steels in Ionic Liquids and in Aqueous Solutions

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    The semiconducting properties of passive films formed on AISI304 steel, thermally at 400°C or anodically in a borate buffer solution, were comparatively studied by capacitance measurements and the usual Mott-Shottky (MS) approach in an aqueous borate buffer solution of pH 9.2 and in BMMITFSI, a room temperature ionic liquid. This ionic liquid was used due to its wide electrochemical window of circa 4.3 V, enabling the verification of the accuracy of the MS approach. Two regions corresponding to p and n-type semiconduction were observed in both electrolytes, but calculated dopant concentrations were not always equal. In the ionic liquid a second deeper donor level was always present, which must be further investigated. ©The Electrochemical Society.No Full Tex

    GA Landsat 5 TM Analysis Ready Data Collection 3

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    Maintenance and Update Frequency: asNeededStatement: This product is derived from the USGS Landsat Collection 1 archive. The Moderate Resolution Imaging Spectroradiometer (MODIS) MCD43A1 Version 6 Bidirectional Reflectance Distribution Function and Albedo (BRDF/Albedo) Model Parameters dataset was provided by the National Aeronautics and Space Administration (NASA). It was produced daily using 16 days of Terra and Aqua MODIS data at 500 m resolution. The ozone data was provided by Environment Canada. The Aerosol Optical Thickness data was provided by the Commonwealth Scientific and Industrial Research Organisation (CSIRO). The Precipitable Water for Entire Atmosphere data was provided by the National Oceanic and Atmospheric Administration (NOAA) / Earth System Research Laboratory (ESRL) / Physical Sciences Division (PSD). The baseline Digital Surface Model (DSM) data produced from the Shuttle Radar Topography Mission (SRTM) was provided by the National Geospatial-Intelligence Agency (NGA). Level 1 Collection 1 data was provided by the United States Geological Survey (USGS)'s Earth Resources Observation and Science (EROS) Center.&lt;b&gt;BACKGROUND&lt;/b&gt;&lt;br/&gt;&lt;p&gt;&lt;br/&gt;&lt;p&gt;The United States Geological Survey's (USGS) Landsat satellite program has been capturing images of the Australian continent for more than 30 years. This data is highly useful for land and coastal mapping studies. &lt;br/&gt;&lt;p&gt;In particular, the light reflected from the Earth’s surface (surface reflectance) is important for monitoring environmental resources – such as agricultural production and mining activities – over time. &lt;br/&gt;&lt;p&gt;We need to make accurate comparisons of imagery acquired at different times, seasons and geographic locations. However, inconsistencies can arise due to variations in atmospheric conditions, sun position, sensor view angle, surface slope and surface aspect. These need to be reduced or removed to ensure the data is consistent and can be compared over time. &lt;br/&gt;&lt;p&gt;&nbsp&lt;/p&gt;&lt;br/&gt;&lt;b&gt;WHAT THIS PRODUCT OFFERS&lt;/b&gt;&lt;br/&gt;&lt;p&gt;&lt;br/&gt;&lt;p&gt;GA Landsat 5 TM Analysis Ready Data Collection 3 takes Landsat 5 Thematic Mapper (TM) imagery captured over the Australian continent and corrects for inconsistencies across land and coastal fringes. The result is accurate and standardised surface reflectance data, which is instrumental in identifying and quantifying environmental change. &lt;br/&gt;&lt;p&gt;&lt;br/&gt;&lt;p&gt;The TM instrument is an advanced, multispectral scanning, Earth resources sensor which is designed to categorise the Earth's surface. It is particularly useful for agricultural applications and identification of land use. &lt;br/&gt;&lt;p&gt;&lt;br/&gt;&lt;p&gt;This product is a single, cohesive Analysis Ready Data (ARD) package, which allows you to analyse surface reflectance data as is, without the need to apply additional corrections. &lt;br/&gt;&lt;p&gt;&lt;br/&gt;&lt;p&gt;It contains three sub-products that provide corrections or attribution information:&lt;br/&gt;&lt;p&gt;&lt;br/&gt;&lt;p&gt;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;1) GA Landsat 5 TM NBAR Collection 3 &lt;br/&gt;&lt;p&gt;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;2) GA Landsat 5 TM NBART Collection 3&lt;br/&gt;&lt;p&gt;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;3) GA Landsat 5 TM OA Collection 3&lt;br/&gt;&lt;p&gt;&lt;br/&gt;&lt;p&gt;The resolution is a 30 m grid based on the USGS Landsat Collection 1 archive

    Reversal of tacrolimus-related hypertrophic obstructive cardiomyopathy 5 years after kidney transplant in a 6-year-old recipient

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    Hypertrophic obstructive cardiomyopathy (HOCM) is an unusual but serious side-effect of tacrolimus (TAC) based immunosuppression primarily affecting pediatric patients after solid organ transplant. TAC-induced HOCM has already been described in patients after liver, bowel and heart transplant shortly after the procedure. Herein, we present the first case report of TAC-induced HOCM in a young renal transplant recipient 5 yr after renal transplant. The condition was diagnosed by ECHO and EKG and successfully treated by discontinuation of TAC followed by conversion to cyclosporine (CsA)

    The dependence of light extraction improvement on optimized surface microstructure for AlGaN-based UVC-LEDs considering TM-polarized emission

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    In order to improve the light extraction of AlGaN-based short wavelength ultraviolet light emitting diodes (DUC-LEDs), a type of microstructure with high aspect ratio is introduced and optimized on the AlN substrate surface. And, particle swarm optimization (PSO) algorithm is used to inverse design of the surface microstructure to maximize the light extraction efficiency (LEE). Considering that the propagation characteristics of TM-polarized light are different from that of TE-polarized light, the optical field distribution and LEE is analyzed for the UVC-LEDs with different TE-polarized component when the optimized surface microstructure is applied. Furthermore, the preparation process tolerance of the high aspect ratio structure is discussed by calculating the LED's LEE when the structural deviation occurs or morphology changes. Simulation results show that, by using the optimized surface microstructure based on parabola cone array, the LEDs' LEE is increased from 4.4% to 8.7% and from 0.4% to 3.7% for TE-polarized and TM-polarized emission, respectively. In addition, it is demonstrated that the light extraction improvement by the surface microstructure has a good tolerance to the structural deviation and morphology. The results are significant for improving light extraction and realizing high efficient short wavelength AlGaN-based UVC-LEDs by designing surface microstructures.Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.ImPhys/Esmaeil Zadeh grou

    Rigor and relevance in empirical TM research: Key issues and challenges Author links open overlay panel

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    This paper aims to offer a critical reflection on the way Talent Management (TM) is investigated in practice, by addressing the key issues regarding the quality (in terms of rigor and relevance) of academic empirical TM research and therefore the critical scrutiny of TM scholars’ work. We will argue that despite the growth in the quantity, the quality of many empirical TM papers is lagging behind and hindering the progress of the academic field of TM. Based on a content analysis of 174 peer-reviewed articles published between 2006 and 2017, the paper outlines nine critical issues regarding the quality of the existent empirical TM research. In order to improve the positioning of the field as well as the impact of TM research on practice itis absolutely necessary for TM scholars to secure the quality of academic empirical TM research. Also, the collaboration between practitioners and scholars should increase.Peer ReviewedPostprint (author's final draft
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