37 research outputs found
Ultrasound Assisted Solvent/Metal Free Synthesis of 3‐Sulfenylindoles Employing TBATB‐Grafted MCM‐48 as a suitable Heterogeneous Catalyst.
Iodine-Catalyzed Mono- and Disulfenylation of Indoles in PEG<sub>400</sub> through a Facile Microwave-Assisted Process
ChemInform Abstract: Benzyltrimethylammoniumfluoride Hydrate: An Efficient Catalyst for One‐Pot Synthesis of Hantzsch 1,4‐Dihydropyridines and Their Aromatization.
Visible‐Light Cercosporin Catalyzed Sulfenylation of Electron‐Rich Compounds with Thiols under Transition‐Metal‐Free Conditions
Correction: Visible-light-induced regioselective sulfenylation of imidazopyridines with thiols under transition metal-free conditions
Correction for ‘Visible-light-induced regioselective sulfenylation of imidazopyridines with thiols under transition metal-free conditions’ by Rajjakfur Rahaman et al., Green Chem., 2018, 20, 141–147.</p
ChemInform Abstract: Metal Free Sulfenylation of Active Methylene Compounds and Indole: TBATB Mediated Synthesis.
1-Benzylsulfanyl-2-[(2-chlorophenyl)diazenyl]benzene
The title compound, C19H15ClN2S, a divalent organosulfur compound belonging to the class of ortho-mercaptoazo compounds, is non-ionic in nature. The azo group in the molecule is moved away from the S atom to attain the stable trans-azo configuration. Here the S atom is not electron deficient, so no intramolecular N...S interaction exists. Due to steric reasons, the molecule is non-planar: the chlorophenyl and benzyl rings are oriented at dihedral angles of 3.21&#8197;(8) and 78.18&#8197;(5)&#176;, respectively, with respect to the thiophenyl ring. There are no hydrogen bonds and the crystal structure is stabilized by van der Waals interactions
Visible-light-induced regioselective sulfenylation of imidazopyridines with thiols under transition metal-free conditions
Visible-light-induced regioselective sulfenylation of imidazopyridines and indoles with thiols under transition metal-free conditions.</p
