177,642 research outputs found
ON THE BALU NUMBERS
In this paper we prove that there are only finitely many Balu numbers
Simulation of thermal plant optimization and hydraulic aspects of thermal distribution loops for large campuses
Following an introduction, the author describes Texas A&M University and its utilities system. After that, the author presents how to construct simulation models for chilled water and heating hot water distribution systems. The simulation model was used in a $2.3 million Ross Street chilled water pipe replacement project at Texas A&M University. A second project conducted at the University of Texas at San Antonio was used as an example to demonstrate how to identify and design an optimal distribution system by using a simulation model. The author found that the minor losses of these closed loop thermal distribution systems are significantly higher than potable water distribution systems. In the second part of the report, the author presents the latest development of software called the Plant Optimization Program, which can simulate cogeneration plant operation, estimate its operation cost and provide optimized operation suggestions. The author also developed detailed simulation models for a gas turbine and heat recovery steam generator and identified significant potential savings. Finally, the author also used a steam turbine as an example to present a multi-regression method on constructing simulation models by using basic statistics and optimization algorithms. This report presents a survey of the author??s working experience at the Energy Systems Laboratory (ESL) at Texas A&M University during the period of January 2002 through March 2004. The purpose of the above work was to allow the author to become familiar with the practice of engineering. The result is that the author knows how to complete a project from start to finish and understands how both technical and nontechnical aspects of a project need to be considered in order to ensure a quality deliverable and bring a project to successful completion. This report concludes that the objectives of the internship were successfully accomplished and that the requirements for the degree of Degree of Engineering have been satisfied
Intern experience at CH���M Hill, Inc.: an internship report
Includes author's vita"Submitted to the College of Engineering of Texas A&M University in partial
fulfillment of the requirement for the degree of Doctor of Engineering."Includes bibliographical referencesA review of the author's internship experience with CH���M HILL, Inc.
during the period September 1975 through May 1976 is presented. During this nine month
internship the author worked as an Engineer II in the Industrial Processes discipline of this
large consulting engineering firm... The author's prime responsibility was as one of three
lead design engineers on the design of a large wastewater treatment facility for a pulp mill
in Hoquiam, Washington owned by ITT Rayonier Inc. The work generally consisted of the design
of individual treatment units and associated piping and pumping. The purpose of the project
was to provide wastewater treatment capabilities that would satisfy the effluent limitations
(standards) imposed upon the mill by the State of Washington Department of Ecology and the
U.S. Environmental Protection Agency. The author's assignment also entailed necessary
interaction with the project manager and other CH���M HILL design engineers and support staff
members, the client's representatives, and representatives of two other consulting engineering
firms working on the project. Thus, the internship position at CH���M HILL provided considerable
experience coordinating the author's work with the work of other engineers, guiding the design
and administrative efforts of a support staff, and interacting regularly with the client and
other consulting firms. This broad exposure to a variety of engineering and organizational
problems provided a valuable educational experience
Intern experience at the Texas Transportation Institute: an internship report
"Submitted to the College of Engineering of Texas A&M University in partial
fulfillment of the requirements for the degree of Doctor of Engineering."Includes vita (leaf 91)Includes bibliographical references (leaf 57)This report discusses the author's engineering experience at the Texas
Transportation Institute (TTI), Texas A&M University from March 1974 through July 1977. A
report of this experience plus twelve additional hours of academic course work were
substituted for an internship according to requirements established by the College of
Engineering. Although the author could not retroactively establish objectives of the type
associated with a typical internship, the work experience gained could be related to the two
general objectives of an intership: 1. To demonstrate an identifiable contribution to the
organization in which the intern served, and 2. To enable the intern to become aware of the
non-technical aspects of working as an engineer in a non-academic environment. While a member
of the Texas Transportation Institute staff, the author worked on a number of projects in the
areas of highway traffic engineering research and the preparation of continuing education
courses for transportation engineering officials. These assignments were contained within the
Urban Transportation Systems Division of TTI. This report delineates the author's contribution
to four particular projects and discusses the technical as well as non-technical experience
gained from each. Having been exposed to more engineering situations than many of the other
Doctor of Engineering students, the author has already formulated some rather specific
milestones for the future. The Doctor of Engineering program is discussed in conjunction with
its potential for helping the author attain these career goals and objectives. Also, some
thoughts are presented regarding the Doctor of Engineering as a viable alternative to the
Ph.D. in preparing for a career in engineering higher education
Environmental Catalysis: Present and Future
Environmental catalysis plays a crucial role in sustainable development by the design of novel catalytic materials and technologies. Several environmental issues are addressed by catalytic processes such as decomposition of pollutants for air, water and soil remediation, hydrogen production, CO2 reduction and biomass valorization, just to name a few. This contribution aims to provide a general overview of the main concepts and current advances in the environmental catalysis field. Special attention has been paid to photocatalysis and electrocatalysis, as sub-areas of catalysis with tremendous potential in sustainable applications, in particular with regard to the promotion of sustainable energies. In this contribution, the partnership between Catalysis and Green Chemistry is presented, in a comprehensive way, as an open research line which is imperative and decisive for a more sustainable future
Solventless mechanochemical preparation of novel magnetic bioconjugates
A solventless mechanochemical approach was employed to obtain a bioconjugate (BSA-DA-Fe2O3) based on bovine serum albumin (BSA) and dopamine (DA) coated iron oxide magnetic nanoparticles. UV-vis measurements of the obtained material showed a distinctive peak at 280 nm which, together with the presence of N on the surface of the nanomaterial (a band at 400 eV in the XPS spectrum) and zeta potential measurements, confirmed the successful immobilization of the protein. Additionally, the presence of two bands at 1652 and 1545 cm-1 in the FT-IR spectra of both BSA and BSA-DA-Fe2O3 and steady-state fluorescence analysis validated that the protein preserved its native-like structure after the mechanochemical milling process. Also the functionalized MNPs preserved their magnetic properties as have been demonstrated by their magnetic susceptibility value
Continuous flow synthesis of high valuable N-heterocycles via catalytic conversion of levulinic acid
Graphitic carbon nitride (g-C3N4) was successfully functionalized with a low platinum loading to give rise to an effective and stable catalytic material. The synthesized g-C3N4/Pt was fully characterized by XRD, N2 physisorption, XPS, SEM-Mapping, and TEM techniques. Remarkably, XPS analysis revealed that Pt was in a dominant metallic state. In addition, XPS together with XRD and N2 physisorption measurements indicated that the g-C3N4 preserves its native structure after the platinum deposition process. g-C3N4/Pt was applied to the catalytic conversion of levulinic acid to N-heterocycles under continuous flow conditions. Reaction parameters (temperature, pressure, and concentration of levulinic acid) were studied using 3 levels for each parameter, and the best conditions were employed for the analysis of the catalyst's stability. The catalytic system displayed high selectivity to 1-ethyl-5-methylpyrrolidin-2-one and outstanding stability after 3 h of reaction
Biomass valorization: Catalytic approaches using benign-by-design nanomaterials
Research on biomass valorization approaches demands endeavors from the scientific community, looking forward to more sustainable and renewable alternatives to the petro-based industry. In this regard, the group FQM-383 (NANOVAL), from University of Cordoba has dedicated many efforts, going from conventional heating approaches to continuous flow strategies, and to the use of unconventional technologies such as microwave and ultrasound irradiations. Moreover, investigations on biomimetic catalysis and photocatalysis have been also directed to the upgrading a biomass residues and derived platform molecules. Importantly, the investigations performed by our research group consider atom, cost and energy efficiency of a process, involving renewable feedstocks and catalytic steps
The long-wavelength view of GG Tau A: rocks in the ring world
We present the first detection of GG Tau A at centimetre wavelengths, made with the Arcminute Microkelvin Imager Large Array at a frequency of 16 GHz (λ = 1.8 cm). The source is detected at >6 σrms with an integrated flux density of S16GHz = 249 ± 45 µJy. We use these new centimetre-wave data, in conjunction with additional measurements compiled from the literature, to investigate the long-wavelength tail of the dust emission from this unusual protoplanetary system. We use an MCMC-based method to determine maximum likelihood parameters for a simple parametric spectral model and consider the opacity and mass of the dust contributing to the microwave emission. We derive a dust mass of Md ~ 0.1 Msun, constrain the dimensions of the emitting region and find that the opacity index at λ > 7 mm is less than unity, implying a contribution to the dust population from grains exceeding ~4 cm in size. We suggest that this indicates coagulation within the GG Tau A system has proceeded to the point where dust grains have grown to the size of small rocks with dimensions of a few centimetres. Considering the relatively young age of the GG Tau association in combination with the low derived disc mass, we suggest that this system may provide a useful test case for rapid core accretion planet formation models
Mechanochemically synthesized supported magnetic fe-nanoparticles as catalysts for efficient vanillin production
Magnetically separable nanocatalysts were synthesized by incorporating iron nanoparticles on a mesoporous aluminosilicate (Al-SBA-15) through a mechanochemical grinding pathway in a single step. Noticeably, magnetic features were achieved by employing biomass waste as a carbon source, which additionally may confer high oxygen functionalities to the resulting material. The resulting catalysts were characterized using X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy, porosimetry, and magnetic susceptibility. The magnetic nanocatalysts were tested in the selective oxidative cleavage reaction of isoeugenol and vanillyl alcohol to vanillin. As a result, the magnetic nanocatalysts demonstrated high catalytic activity, chemical stability, and enormous separation/reusability qualities. The origin of catalytic properties and its relationship with the iron oxide precursor were analyzed in terms of the chemical, morphological, and structural properties of the samples. Such analysis allows, thus, to highlight the superficial concentration of the iron entities and the interaction with Al as key factors to obtain a good catalytic response
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