4,631 research outputs found
Petr Simon (1944-2018)
No full textThis article is a reflection on the mathematical legacy of Professor Petr Simon.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Analysi
Abundance of bacterial 16S rRNA sequences, genomes and DNA in forest litter and soil.
No full text<p>Relative abundance of bacterial 16S rRNA sequences in the amplicon pool from <i>Picea abies</i> litter and soil (Baldrian et al., 2012), and estimates of the relative abundance of bacterial genomes and DNA. The estimates were calculated using the values of 16S rRNA copy numbers and genome sizes of the closest hits to each bacterial OTU.</p
Centralization of treasury management 2010
No full textThe book consists of five parts: 1. Treasury management and its responsibilities (Chapter 1‐4); 2. Decentralized treasury (Chapter 5); 3. Different phases of the centralization (Chapter 6‐9); 4. Outsourcing (Chapter 10) 5. Regional treasury centres (Chapter 11); 6. Best practices in a bank (Chapter 12); In the first part, the author describes the treasury management focusing on its three core responsibilities, such as assets and liabilities management, cash management, and financial risk management. The second part zooms in on decentralized treasury and decisions about the appropriate degree of centralization/decentralization of the treasury activities. Then we focus on the different phases of the process of centralization, from central interest rate and foreign exchange management through centralization of cash and liquidity management, then transaction processing up to fully centralized treasury. In part four we continue by discussing outsourcing as the next stage following centralization to achieve additional economic benefits. The fifth part contains especially a number of the location criteria, both tax and non‐tax, that must be evaluated during consideration where to establish the regional treasury centre. The last part deals with banking best practices in cash pooling from the point of view of the author that works in one of the top banks in Central and Eastern Europe region
Wood decomposition is increased by insect diversity, selection effects, and interactions between insects and microbes
No full textThe data is for the publication:Jia-Yun Zou, Marc W. Cadotte, Claus Bässler, Roland Brandl, Petr Baldrian, Werner Borken, Elisa Stengel, Ya-Huang Luo, Jörg Müller, Sebastian Seibold*. 2023. Wood decomposition is increased by insect diversity, selection effects, and interactions between insects and microbes. Ecology*corresponding author: [email protected]</p
Cyclometalation of phenylpyridines with a ferrocenyl group
No full textNázev práce: Cyklometalace fenylpyridinů s ferrocenylovým substituentem Autor: Bc. Petr Harmach Katedra: Katedra anorganické chemie Vedoucí diplomové práce: prof. RNDr. Petr Štěpnička, Ph.D., DSc. Abstrakt: Cílem této práce byla příprava cyklometalovaných komplexů fenylpyridinů s ferrocenylovým substituentem. Cyklometalované komplexy mají široké spektrum využití, kdy jedním z nejvýznamnějších je použití v katalýze. Připraveny byly iridité a rhodité cyklometalované komplexy s elektrondonorními nebo elektronakceptorními skupinami na pyridinovém kruhu. Všechny tyto látky byly charakterizovány 1 H a 13 C{1 H} NMR spektroskopií, hmotnostní spektrometrií, elementární analýzou a cyklickou voltametrií. U dvou připravených látek byly jejich struktury potvrzeny pomocí metody difrakce rentgenového záření na monokrystalech. Klíčová slova: cyklometalace, pyridin, C-H aktivace, ferrocenTitle: Cyclometalation of phenylpyridines with a ferrocenyl group Author: Bc. Petr Harmach Department: Katedra anorganické chemie Supervisor: prof. RNDr. Petr Štěpnička, Ph.D., DSc. Abstract: The objective of this thesis was the synthesis of cyclometalated complexes of phenylpyridine with a ferrocenyl group. Cyclometalated complexes have a wide range of application, where one of the most important is the use in catalysis. Iridium(III) and rhodium(III) cyclometalated complexes were prepared containing electron-donating or electron-accepting groups on the pyridine ring. All newly prepared complexes were characterized by 1 H a 13 C{1 H} NMR spectroscopy, mass spectrometry, elemetal analysis and cyclic voltammetry. The structures of two complexes were determined by single-crystal X-ray diffraction analysis. Key words: cyclometalation, pyridine, C-H activation, ferroceneDepartment of Inorganic ChemistryKatedra anorganické chemiePřírodovědecká fakultaFaculty of Scienc
Fungal communities are passengers in community development of dune ecosystems, while bacteria are not
No full textAn increasing number of studies of above-belowground interactions provide a fundamental basis for our understanding of the coexistence between plant and soil communities. However, we lack empirical evidence to understand the directionality of drivers of plant and soil communities under natural conditions: 'Are soil microorganisms driving plant community functioning or do they adapt to the plant community?' In a field experiment in an early successional dune ecosystem, we manipulated soil communities by adding living (i.e., natural microbial communities) and sterile soil inocula, originating from natural ecosystems, and examined the annual responses of soil and plant communities. The experimental manipulations had a persistent effect on the soil microbial community with divergent impacts for living and sterile soil inocula. The plant community was also affected by soil inoculation, but there was no difference between the impacts of living and sterile inocula. We also observed an increasing convergence of plant and soil microbial composition over time. Our results show that alterations in soil abiotic and biotic conditions have long-term effects on the composition of both plant and soil microbial communities. Importantly, our study provides direct evidence that soil microorganisms are not "drivers" of plant community dynamics. We found that soil fungi and bacteria manifest different community assemblies in response to treatments. Soil fungi act as "passengers," that is, soil microorganisms reflect plant community dynamics but do not alter it, whereas soil bacteria are neither "drivers" nor "passengers" of plant community dynamics in early successional ecosystems. These results are critical for understanding the community assembly of plant and soil microbial communities under natural conditions and are directly relevant for ecosystem management and restoration.Environmental BiologyPlant science
Adaptivní volba parametrů stabilizačních metod pro rovnice konvekce-difúze
No full textTitle: Adaptive choice of parameters in stabilization methods for convection- diffusion equations Author: Bc. Petr Lukáš (e-mail: [email protected]) Department: Department of Numerical Mathematics Supervisor: Doc. Mgr. Petr Knobloch, Dr. (e-mail: [email protected]) Abstract: The aim of the work is to propose suitable approaches for adap- tive choice of parameters in stabilization methods for convection-difusion equations discretized by the finite element method. We introduce the L-SR1 method, compare it with other nonlinear methods of minimizing functions with large number of variables, and introduce and compare the adaptive methods based on minimizing of the error indicator. Keywords: Adaptive choice of parameters, finite element method, stabiliza- tion methods, convection-diffusion equation, L-SR1 method, error indicato
Cyclometalation of phenylpyridines with a ferrocenyl group
No full textTitle: Cyclometalation of phenylpyridines with a ferrocenyl group Author: Bc. Petr Harmach Department: Katedra anorganické chemie Supervisor: prof. RNDr. Petr Štěpnička, Ph.D., DSc. Abstract: The objective of this thesis was the synthesis of cyclometalated complexes of phenylpyridine with a ferrocenyl group. Cyclometalated complexes have a wide range of application, where one of the most important is the use in catalysis. Iridium(III) and rhodium(III) cyclometalated complexes were prepared containing electron-donating or electron-accepting groups on the pyridine ring. All newly prepared complexes were characterized by 1 H a 13 C{1 H} NMR spectroscopy, mass spectrometry, elemetal analysis and cyclic voltammetry. The structures of two complexes were determined by single-crystal X-ray diffraction analysis. Key words: cyclometalation, pyridine, C-H activation, ferrocen
Synthesis of gold(I) carbene complexes from isocyanoferrocene
No full textTitle: Synthesis of gold(I) carbene complexes from isocyanoferrocene Author: Petr Harmach Department: Katedra anorganické chemie Supervisor: prof. RNDr. Petr Štěpnička, Ph.D., DSc. Abstract: The objective of this bachelor thesis was the synthesis of gold(I) carbene complexes. These complexes were synthetised from a newly prepared gold(I)-isocyanoferrocene complex and also directly from isocyanoferrocene. Carbene complexes were obtained from primary and secondary amines, and therefore complexes contain disubstituted or trisubstituted diaminocarbene moieties. All newly prepared complexes were characterized by NMR spectroscopy, mass spectrometry, elemental analysis and infrared spectroscopy. The structures of the majority of the prepared complexes were confirmed by single-crystal X-ray diffraction analysis. Key words: isocyanides, ferrocene, carbenes, gold(I) complexe
Homologous ferrocene phosphines
No full textTitle: Homologous ferrocene phosphines Author: Bc. Petr Vosáhlo Department: Department of Inorganic Chemistry Supervisor: prof. RNDr. Petr Štěpnička, Ph.D., DSc. Abstract: This thesis describes the synthesis and coordination behaviour of ferrocene diphosphines derived from 1,1'-bis(diphenylphosphino)ferrocene (dppf). Dppf is one of the most succesful ferrocene ligands, which can be used in various metal-catalyzed reactions. This study aimed to prepare analogous ligands with one dialkylphosphino substituent and one (diphenylphosphino)methyl group. These ligands were oxidized by KSeCN to afford the corresponding phosphinoselenides. The phosphinoselenides were used to assess sigma-donor abilities by measuring the coupling constant 1 JSeP via 31 P NMR spectroscopy. Lastly, the coordination behaviour of these ligands in palladium complexes was studied. The homologous ligands usually formed a mixtures containing a chelate complex and dimeric species with trans- coordinated ligands. Key words: ferrocene, phosphines, homologous ligands, palladium(II) complexes, structure elucidation
- …
