68 research outputs found

    Hydrogen leakages in a congested aircraft environment: a CFD simulation method

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    The option of using hydrogen as a fuel for propulsion of aircraft has been investigated in the recent past especially in combination with long endurance unmanned mission targets (Helinet, Helios). This application has proved to be challenging mostly due to the low volumetric density of hydrogen, which needs to be compressed at very high pressures to be confined in the narrow volumes allowed by aircrafts structures. Aerial, as well as automotive, applications of hydrogen pose also the issue of weight for the total storage solution adopted: high pressures may mean thick layers for vessels and consequently high weights for unit of mass of hydrogen stored. Composite materials have helped in reducing the weight but remain tough to be adopted for vessels large enough to store the hydrogen mass necessary for long trips. Liquid hydrogen has only been adopted so far for aerospace applications and just for boosting rather than for endurance. Instead, hydrogen can be efficiently used for fuelling auxiliary systems on board and for ground services, helping to reduce the environmental impact, also regarding the idling phase. Fuel cells that are supplied with hydrogen can provide the electricity needed by all the auxiliary equipment, from air conditioning systems, to controls and avionics, to lighting and security services. Although smaller quantities of hydrogen are needed on board to supply only the auxiliaries rather than for propulsion, still there is a need for pressurising the gas and so to have a pressurised feed line that runs into the congested environment of an aircraft where ventilation is anyway usually present. In view of the experience gained in the oil and gas offshore sector, where flammable and pressurised gases may be released due to failures in the feed lines, we propose an innovative approach to investigate the possible hazards deriving from the use of pressurised hydrogen in aeronautics. Hydrogen releases may happen due to failures all along the lines but, statistically, ruptures are more frequent in lower pressures sections that are potentially less protected. A hydrogen supply line can cover pressures that range from 350 bars of the storage vessel to the nearly ambient pressure when it supplies the fuel cells. This induces to take greater care of possible mid-pressure (10-15 bars) releases and of their consequences. Ruptures are seldom catastrophic, while more often they are represented by small diameter cracks. The release through these ruptures is supersonic and it soon slows down also due to the scattering with obstacles in the aircraft environment. Modelling of the entire phenomenon is a challenging task for Computational-Fluid-Dynamic analysts as some variables such as pressure, and therefore velocity, have too strong variations throughout the domain. Yet, CFD remains the best tool to predict the dispersion and possibly the dangerous (i.e. above the - very low- flammability limit of hydrogen) accumulation of gas. Our proposal is to split the phenomenon in two phases and to study them separately with a coupling based on the parameters that are more relevant to describe the evolution: velocity and concentration. First, the supersonic release of hydrogen from the rupture, and the consequent compressible effects, are modelled in a domain that is large enough to contain the deceleration of the gas up to dispersion-like rates: this domain is, however, smaller than the full domain where we wish to study the entire phenomenon. Second, data related to speed and concentration calculated on the surface of this domain are given as boundary conditions for the simulation of the dispersion phase. Preliminary applications of this method to hydrogen releases from 10 mm hole ruptures at a pressure of 10 bar have provided interesting results especially with the supersonic release phase, that is the most challenging for the CFD simulation due to the intrinsic characteristics of hydrogen as a very light gas. In particular, addressing the supersonic release phase may allow estimating the effect of impact of the jet release onto the first obstacle (in the form of thermal stresses). The final coupling of the two phases can provide a dispersion pattern within a congested environment that can be validated in field tests, in the same way as it is being done with this method applied to natural gas releases in offshore platforms

    CFD modelling of an accidental pressurised gas release

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    Risk assessment usually requires to simulate hundreds of different accidental scenarios in order to identify the most potentially critical events. The objective of this work is to improve and optimize the use of a Two Steps CFD model in order to minimise the number of simulations needed this is achieved thanks to a sensitivity analysis on the main parameters characterising a release event in a typical congested industrial environment

    A novel approach to high-pressure gas releases simulations

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    Risk-relevant plants like Oil & Gas (O&G) or nuclear ones are subjected to strict safety regulations. Risk Assessment is mandatory for these plants, and the damage quantification is a crucial step which has to be carefully addressed. Nowadays the state of practice for consequences estimation entails the use of semi-empirical methods which permit a fast evaluation of the large number of accidental scenarios needed for a Quantitative Risk Assessment (QRA). However, in case of large and congested industrial environments like offshore platforms or equipment inside nuclear primary containment buildings, the aforementioned methods usually lead to an overestimation of the damage areas, for example because they neglect the space congestion which highly affects the accident evolution. A more accurate analysis can be performed using the Computational Fluid Dynamics (CFD), nonetheless its high computational cost represents an important drawback. In this work a CFD approach, called Source Box Accident Model (SBAM), is presented. It models high-pressure gas releases (> 10 bar) in congested environments guaranteeing a good computational cost-accuracy compromise. The aim of SBAM is to permit a fast consequences estimation (evaluation of flammable/toxic areas, etc.) via CFD, in order to have a simulations time compatible with the plants design schedule. The long-term objective is to integrate the CFD contribution in a safety driven design process. SBAM is based on the splitting of the multi-physics and multiscale phenomena characterizing the accident: the initial supersonic compressible release and the successive low speed dispersion. The first one is simulated in a small domain called Source Box (SB) and the second one in the case study domain. The two simulations are coupled in a suitable way, through proper parameters which are extensively discussed. This work presents a detailed description of SBAM and two different analyses: a sensitivity study on the coupling parameters and a numerical benchmark which uses a standard CFD simulation as reference. The sensitivity analysis shows that the coupling is a crucial step of the method and the coupling parameters must be treated in the most accurate way. The numerical benchmark shows that SBAM is not introducing significant errors with respect to a standard CFD simulation and in addition, permits a relevant simplification in the simulation setup and computational cost reduction

    Chemical composition and yield of rhizome biomass of Arundo donax L. grown for biorefinery in the Mediterranean environment

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    The contribution of the rhizome to productivity of fermentable sugars and the detailed composition of rhizomes were analyzed in three mature stands of Arundo donax L. cultivated in three locations of variable fertility in the South of Italy. Although the average yearly aboveground dry biomass and rhizome amount showed large and significant differences among sites, (15.3 and 2.6 Mg ha−1 year−1 of rhizomes in the most and less productive sites respectively), rhizomes of all sites had more than 30% of the dry matter (DM) as non-structural carbohydrates (NSC). Sucrose and starch were the most abundant NSC but measurable amounts of glucose, fructose, galactose and of the valuable trisaccharide raffinose were also present. The amount of NSC in rhizomes affected their content of dry mater, and water extractives. The ash content also varied significantly among cultivation sites; the highest amount was recorded in rhizomes of the most productive site (Acerra). The abundance in cell wall components of rhizomes was similar to that of published values for the above ground biomass. The present results demonstrate that NSC content in rhizomes of mature stands is a conserved trait. Hence, rhizome biomass, thanks to its quantity and high fermentable sugars content, should be considered as a relevant fraction of the A. donax crop product whose utilization can increase the productivity and the environmental fingerprint of this crop, in view of its biomass utilization in biorefinery

    CFD Modelling of Pressurized Gas Releases: Sensitivity Analysis of Driving Parameters

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    The consequences analysis is a crucial aspect of the Risk Assessment, especially for Oil & Gas structures, where hundreds of accidental scenarios must be simulated. This work investigates the accidental release of high-pressure flammable gas in a congested offshore environment considering multi-physics and multi-scale nature of the phenomenon. Initially, the flow results supersonic with compressible effects and then it evolves in a subsonic dispersion. To handle this change of physics, a Computational Fluid Dynamics (CFD) two steps approach is developed at the SEADOG laboratory in Politecnico di Torino. This approach imposes two simulations: the first one considers the compressible phenomena in a small domain called Source Box (SB), the second one considers the gas dispersion in the platform. The advantage is to use the results of the first simulation as an input for several dispersion simulations. The aim is to compile a library of plausible SB and to evaluate the consequences of an accidental scenario selecting the proper SB for the dispersion simulation, allowing a timesaving. This work is focused on the optimization of the number of SB to construct a SB library. The objective of this work is to achieve a sensitivity analysis on the input parameters (release pressure, hole diameter, distance and dimension of an obstacle inside the SB) in order to optimize the number of SB to be simulated reducing the computational effort

    Phosphoenolpyruvate carboxykinase and gluconeogenesis in grape pericarp

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    Glycolysis from sugars is necessary at all stages of development of grape pericarp, and this raises the question as to why gluconeogenesis from malate occurs. Phosphoenolpyruvate carboxykinase (PEPCK) is required for gluconeogenesis in grape pericarp. In this study we determined the abundance of PEPCK protein and activity in different parts of grape pericarp during its development. Both PEPCK protein and activity were present throughout development, however, in both the skin and the flesh their abundance increased greatly at the start of ripening. This coincided with the onset of the decrease in the malate content of the berry. The location of PEPCK in the pericarp at different stages of development was determined using both immunohistochemistry and dissection. We provide a possible explanation for the occurrence of gluconeogenesis in grape pericarp

    The organic acids that are accumulated in the flesh of fruits: occurrence, metabolism and factors affecting their contents - a review

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    Organic acids are abundant constituents of ripe fruits and are responsible for their sourness. In addition, they contribute to their flavour. In many fruits, the most abundant organic acids are malic and citric. The aims of this review are two-fold. The first is to provide a clear overview of malic and citric acids in the flesh of fruits. The abundance of different organic acids in commercially grown fruits is described. How this abundance changes during fruit development is outlined. The metabolic pathways used in the synthesis and dissimilation of malic and citric acids in fruits are described. The functions of malic and citric acids in the flesh of fruits are discussed. Secondly, how environmental and cultural practices can alter the organic acid content of fruits is considered
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