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, 3150 (2001)]
It is pointed out that a recently published study [Phys. Plasmas 8, 3150 (2001)] of the effects of magnetic shear and shear flow on dust-drift waves has already been studied earlier. Further, the results obtained in Phys. Plasmas 8, 3150 (2001) are erroneous as the shear flow effect has been included in an inappropriate manner. (C) 2002 American Institute of Physics.status: Publishe
Astronomische Nachrichten, nos 3145-3150
R. R. Astronomische Nachrichten, nos 3145-3150. In: Bulletin astronomique, tome 10, 1893. pp. 305-312
Santa Fe (ATSF) 3150 (neg)
A photograph negative showing Santa Fe 3150, 2-8-2, California
"Dibujar discursos, construir imaginarios. Prensa y caricatura política en España (1836-1874)"
Mechanistic Investigations into the Palladium-Catalyzed Decarboxylative Allylic Alkylation of Ketone Enolates Using the PHOX Ligand Architecture
Palladium-catalyzed asymmetric allylic alkylation has become a large and important field for chemical synthesis. Many methodologies in this field offer mild conditions under which challenging and important molecular features can be reliably synthesized, including chiral all-carbon quaternary stereocenters. As a result, palladium- catalyzed asymmetric allylic alkylation has found significant use in total synthesis, and growing use in industry. While the general process of palladium-catalyzed asymmetric allylic alkylation has been studied for decades, there have been a number of recent modifications and developments, such as asymmetric versions of decarboxylative allylic alkylation procedures that are not yet well understood. The development of future implementations and improvements to palladium-catalyzed asymmetric allylic alkylation and related methodologies is expected to be facilitated by a better understanding of these more recent developments, and thus further mechanistic investigation is warranted.
Reported herein is a set of investigations into the palladium-catalyzed decarboxylative asymmetric allylic alkylation of ketone enolates using the PHOX ligand architecture. By monitoring the reaction via 31P NMR, a series of previously unidentified key intermediates is discovered. Two representatives of these key intermediates are isolated and characterized. The solution behavior of these species under reaction-like conditions is studied along with a few novel and related complexes. The role of these intermediates and their impact on the behavior of the reaction and product formation is discussed. Previously confounding experimentally observed behavior for this methodology is rationalized via the properties elucidated for these discovered intermediates.</p
El laberinto español de la modernidad política: es reseña de: MENÉNDEZ, M.; ROBLES, A. (eds.). "Pensamiento político en la España contemporánea". Madrid: Trotta, 2013
Recensión de: Manuel Menéndez Alzamora y Antonio Robles Egea (eds.), Pensamiento político en la España contemporánea, Madrid, Trotta, 2013.Review of: Manuel Menéndez Alzamora y Antonio Robles Egea (eds.), Pensamiento político en la España contemporánea, Madrid, Trotta, 2013
Block Card 3150 Talmadge Road
This image was produced by the Auditor's Office in Lucas County, Ohio for tax assessment purposes. Associated dates are approximate. Descriptive terms related to this photograph include: Ranch houses | 3150 Talmadge Road (Toledo, Ohio) | Dwelling | Westgate Area (Toledo, Ohio
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